Fluorescent carbon quantum dots (CDs) are synthesized and employed as fluorescent nanochemosensors for selective detection of amino acids. A detailed investigation of excitation−emission maps revealed that the fluorescence properties of CDs are intensely and strongly influenced by the interaction at the surface with different amino acids. The discrimination capability was demonstrated by tensor rank decomposition of the differences induced by the surface reaction in the excitation−emission maps and by means of a common machine learning approach based on artificial neural networks.
We have developed a novel experimental method, which enables quantitative determination of interaction forces between interfacial nanoparticles as a function of the inter-particle distance at liquid interfaces.
A bioinspired method of communication among biodevices based on fluorescent nanoparticles is herein presented. This approach does not use electromagnetic waves but rather the exchange of chemical systems—a method known as molecular communication. The example outlined was based on the fluorescence properties of carbon dots and follows a circular economy approach as the method involves preparation from the juice of lemon waste. The synthesis is herein presented, and the fluorescence properties and diffusion coefficient are evaluated. The application of carbon dots to molecular communication was studied from a theoretical point of view by numerically solving the differential equation that governs the phenomenon. The theoretical results were used to develop a prototype molecular communication platform that enables the communication of simple messages via aqueous fluids to a fluorescence-detecting biodevice receiver.
The lack of methodologies which enable us to measure
forces acting
between nanomaterials is one of the factors limiting the full comprehension
of their behavior and their more effective exploitation in new devices.
Here we exploit the irreversible adsorption of surfactant-decorated
nanoparticles at the air/water interface to investigate interparticle
forces and the effect of the surfactant structure on them. We measured
the interparticle repulsive forces as a function of the modulation
of the interparticle distance by simultaneously performing compression
isotherms and the grazing incidence small-angle X-ray scattering (GISAXS)
structural characterization of the monolayers at water–vapor
interfaces. Our results demonstrate that the short-range interparticle
forces are strongly affected by the presence of the organic ligands,
which are shown to be able to influence the interparticle repulsions
even when added in micromolar amounts. In particular, we demonstrate
the predominant steric nature of short-range forces, which are accounted
for in terms of the compression-induced stretched-to-coiled conformational
transition of the ligand hydrophobic tail.
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