This study reports for the first time the use of a red-emitting AIEgen, i.e. TPE-AC, for the realization of efficient luminescent solar concentrators (LSCs) based on poly(methyl methacrylate) (PMMA) and polycarbonate (PC) thin films (25 ± 5 μm). TPE-AC is an AIEgen with D–A features that absorbs visible light in the range between 400 and 550 nm and emits fluorescence peaked at 600–620 nm, with a maximum quantum yield (QY) of 50% when dispersed (0.1–1.5 wt%) in PMMA and PC matrices. QY and lifetime investigations demonstrated that fluorescence quenching occurred with varying the TPE-AC concentration, even if the optical features were still significant even at the highest fluorophore content. Study of the LSCs’ performances yielded worthy optical efficiencies of 6.7% for the TPE-AC/PC systems due to their superior light harvesting features and the compatibility of the AIEgen within the PC matrix
High dielectric contrast polymer dielectric mirrors are used to recycle non-absorbed photons in organic luminescent solar concentrators. A 10% increase in the concentrator optical efficiency is found and retained upon doubling its size paving the way to lightweight and cheap building integrated photovoltaic systems.
We present a processing
method, based on the multivariate curve
resolution approach (MCR), to denoise 2D solid-state NMR spectra,
yielding a substantial S/N ratio increase while preserving the lineshapes
and relative signal intensities. These spectral features are particularly
important in the quantification of silicon species, where sensitivity
is limited by the low natural abundance of the
29
Si nuclei
and by the dilution of the intrinsic protons of silica, but can be
of interest also when dealing with other intermediate-to-low receptivity
nuclei. This method also offers the possibility of coprocessing multiple
2D spectra that have the signals at the same frequencies but with
different intensities (e.g.: as a result of a variation in the mixing
time). The processing can be carried out on the time-domain data,
thus preserving the possibility of applying further processing to
the data. As a demonstration, we have applied Cadzow denoising on
the MCR-processed FIDs, achieving a further increase in the S/N ratio
and more effective denoising also on the transients at longer indirect
evolution times. We have applied the combined denoising on a set of
experimental data from a lysozyme–silica composite.
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