Breccia-filled eruption conduits are dynamic systems where pressures frequently exceed critical thresholds, generating earthquakes and transmitting fluids. To assess the dynamics of breccia-filled conduits, we examine lava, ash tuff, and hydrothermal breccia ballistics with varying alteration, veining, fractures, and brecciation ejected during the 27 April 2016 phreatic eruption of Whakaari/White Island. We measure connected porosity, strength, and permeability with and without tensile fractures at a range of confining pressures. Many samples are progressively altered with anhydrite, alunite, and silica polymorphs. The measurements show a large range of connected porosity, permeability, and strength. In contrast, the cracked samples show a consistently high permeability. The cracked altered samples have a permeability more sensitive to confining pressure than the unaltered samples. The permeability of our altered ballistics is lower than surface rocks of equivalent porosity, illustrating that mineral precipitation locally blocked pores and cracks. We surmise that alteration within the conduit breccia allows cracks to form, open and close, in response to pore pressure and confining pressure, providing a mechanism for frequent and variable fluid advection pulses to the surface. This produces temporally and spatially variable geophysical and geochemical observations and has implications for volcano monitoring for any volcano system with significant hydrothermal activity.

<p>IODP Expedition 379 to the Amundsen Sea continental rise recovered latest Miocene-Holocene sediments from two sites on a drift in water depths >3900m. Sediments are dominated by clay and silty clay with coarser-grained intervals and ice-rafted detritus (IRD) (Gohl et al. 2021, doi:10.14379/iodp.proc.379.2021). Cobble-sized dropstones appear as fall-in, in cores recovered from sediments >5.3 Ma.  We consider that abundant IRD and the sparse dropstones melted out of icebergs formed due to Antarctic ice-sheet calving events. We are using petrological and age characteristics of the clasts from the Exp379 sites to fingerprint their bedrock provenance. The results may aid in reconstruction of past changes in icesheet extent and extend knowledge of subglacial bedrock.</p><p>Mapped onshore geology shows pronounced distinctions in bedrock age between tectonic provinces of West or East Antarctica (e.g. Cox et al. 2020, doi:10.21420/7SH7-6K05; Jordan et al. 2020, doi.org/10.1038/s43017-019-0013-6). This allows us to use geochronology and thermochronology of rock clasts and minerals for tracing their provenance, and ascertain whether IRD deposited at IODP379 drillsites originated from proximal or distal Antarctic sources. We here report zircon and apatite U-Pb dates from four sand samples and five dropstones taken from latest Miocene, early Pliocene, and Plio-Pleistocene-boundary sediments. Additional Hf isotope data, and apatite fission track and <sup>40</sup>Ar/<sup>39</sup>Ar Kfeldspar ages for some of the same samples help to strengthen provenance interpretations.</p><p>The study revealed three distinct zircon age populations at ca. 100, 175, and 250 Ma. Using Kolmogorov-Smirnov (K-S) statistical tests to compare our new igneous and detrital zircon (DZ) U-Pb results with previously published data, we found strong similarities to West Antarctic bedrock, but low correspondence to prospective sources in East Antarctica, implying a role for icebergs calved from the West Antarctic Ice Sheet (WAIS). The ~100 Ma age resembles plutonic ages from Marie Byrd Land and islands in Pine Island Bay.  The ~250 and 175 Ma populations match published mineral dates from shelf sediments in the eastern Amundsen Sea Embayment as well as granite ages from the Antarctic Peninsula and the Ellsworth-Whitmore Mountains (EWM). The different derivation of coarse sediment sources requires changes in iceberg origin through the latest Miocene, early Pliocene, and Plio/Pleistocene, likely the result of changes in WAIS extent.</p><p>One unique dropstone recovered from Exp379 Site U1533B is green quartz arenite, which yielded mostly 500-625 Ma detrital zircons. In visual appearance and dominant U-Pb age population, it resembles a sandstone dropstone recovered from Exp382 Site U1536 in the Scotia Sea (Hemming et al. 2020, https://gsa.confex.com/gsa/2020AM/meetingapp.cgi/Paper/357276). K-S tests yield high values (P ≥ 0.6), suggesting a common provenance for both dropstones recovered from late Miocene to Pliocene sediments, despite the 3270 km distance separating the sites. Comparisons to published data, in progress, narrow the group of potential on-land sources to exposures in the EWM or isolated ranges at far south latitudes in the Antarctic interior.  If both dropstones originated from the same source area, they could signify dramatic shifts in the WAIS grounding line position, and the possibility of the periodic opening of a seaway connecting the Amundsen and Weddell Seas.</p>

Unconsolidated artificial ground is an ever‐increasing feature on the Earth's surface but it poses various challenges such as pollutant release and ground instability. The process of lithification could be an important factor in changing the properties of artificial ground and ameliorating these challenges. In this study, a lithified deposit of a furnace slag associated with a former iron and steel works in Scotland was analysed to determine the mechanisms and drivers of lithification. Scanning electron microscope analysis showed that Ca leached from around the edges of clasts of slag through reaction of the chemically unstable slag with water from an adjacent water body. Dissolution of Ca (and OH−) from the slag caused the water in contact with the slag to become hyperalkaline, facilitating ingassing and hydroxylation of CO2 from the atmosphere (fingerprinted through carbon isotope analysis). Reaction of the dissolved Ca and CO2 led to precipitation of calcite. Scanning electron microscope analysis showed the calcite is distributed between slag clasts, forming rims around clasts and cementing clasts together into a solid rock‐like mass. Understanding the mechanisms and drivers of lithification in artificial ground will be important, given its widespread nature particularly in urban areas where artificial ground is the substrate of most development.

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