Glass foams have great potential for several technological applications, for example, filters and thermal or acoustic insulators. Sodium hydroxide is an efficient foaming agent to obtain glass foams with high level of porosity. However, the control of variables that influences on structure, type, and size of pores of glass foams is necessary.This study evaluates the influence of composition and process parameters on glass foams based on soda-lime glass waste, sodium hydroxide, and borax. Experiments were conducted using factorial designs. According to the experimental conditions, bulk density varied from 0.16 to 0.79 g cm −3 and maximum porosity of 92%. Amounts of NaOH and borax in addition to sintering temperature are the main variables of the foaming process. The role of NaOH content is to reduce the density and closed porosity of glass foams associated with an increase in their open porosity. The addition of borax with low NaOH amount promoted densification and pore closure in glass foams. NaOH and borax content allows controlling the type of predominant porosity on foams (open or closed porosity). Glass foams were resistant to sulfuric acid, hydrochloric acid, and nitric acid in diluted solutions. These results allow controlling the pore structure of glass foams for different applications. K E Y W O R D Sdensity, glass, glass foam, porous materials, sodium/sodium compounds