A reversible carbon-boron bond formation has been observed in the reaction of the coordinatively unsaturated, cyclometalated, Pt(II) complex [Pt(ItBuiPr’)(ItBuiPr)][BArF], 1, with tricoordinated boranes HBR2. X-ray diffraction studies provided structural snap-shots...
Dibenzo[b,d]azepines featuring axially chiral 7-member-bridged biaryls have been prepared by asymmetric reductive or borylative cyclizations using copper catalysis.
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