The evaluation of the radiation field inside a slurry reactor constitutes a central step in the
study of photocatalytic reactions. This task can be achieved by solving the radiative transfer
equation (RTE) for the system under study. To solve the RTE, three optical properties of the
catalyst suspensions are needed: the absorption coefficient, the scattering coefficient, and the
phase function for scattering. In the present work, a novel experimental method to measure the
optical properties of aqueous titanium dioxide (TiO2) suspensions is proposed. The method
involved diffuse reflectance and transmittance spectrophotometric measurements of the catalyst
suspensions, the evaluation of the radiation field in the sample cell, and the application of a
nonlinear optimization program to adjust the model predictions to the experimental data. Three
commercial brands of TiO2 were investigated: Aldrich, Degussa P25, and Hombikat UV 100.
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