An intercomparison of radiance and irradiance ocean color radiometers (the second laboratory comparison exercise—LCE-2) was organized within the frame of the European Space Agency funded project Fiducial Reference Measurements for Satellite Ocean Color (FRM4SOC) May 8–13, 2017 at Tartu Observatory, Estonia. LCE-2 consisted of three sub-tasks: (1) SI-traceable radiometric calibration of all the participating radiance and irradiance radiometers at the Tartu Observatory just before the comparisons; (2) indoor, laboratory intercomparison using stable radiance and irradiance sources in a controlled environment; (3) outdoor, field intercomparison of natural radiation sources over a natural water surface. The aim of the experiment was to provide a link in the chain of traceability from field measurements of water reflectance to the uniform SI-traceable calibration, and after calibration to verify whether different instruments measuring the same object provide results consistent within the expected uncertainty limits. This paper describes the third phase of LCE-2: The results of the field experiment. The calibration of radiometers and laboratory comparison experiment are presented in a related paper of the same journal issue. Compared to the laboratory comparison, the field intercomparison has demonstrated substantially larger variability between freshly calibrated sensors, because the targets and environmental conditions during radiometric calibration were different, both spectrally and spatially. Major differences were found for radiance sensors measuring a sunlit water target at viewing zenith angle of 139° because of the different fields of view. Major differences were found for irradiance sensors because of imperfect cosine response of diffusers. Variability between individual radiometers did depend significantly also on the type of the sensor and on the specific measurement target. Uniform SI traceable radiometric calibration ensuring fairly good consistency for indoor, laboratory measurements is insufficient for outdoor, field measurements, mainly due to the different angular variability of illumination. More stringent specifications and individual testing of radiometers for all relevant systematic effects (temperature, nonlinearity, spectral stray light, etc.) are needed to reduce biases between instruments and better quantify measurement uncertainties.

An intercomparison of radiance and irradiance ocean color radiometers (The Second Laboratory Comparison Exercise—LCE-2) was organized within the frame of the European Space Agency funded project Fiducial Reference Measurements for Satellite Ocean Color (FRM4SOC) May 8–13, 2017 at Tartu Observatory, Estonia. LCE-2 consisted of three sub-tasks: 1) SI-traceable radiometric calibration of all the participating radiance and irradiance radiometers at the Tartu Observatory just before the comparisons; 2) Indoor intercomparison using stable radiance and irradiance sources in controlled environment; and 3) Outdoor intercomparison of natural radiation sources over terrestrial water surface. The aim of the experiment was to provide one link in the chain of traceability from field measurements of water reflectance to the uniform SI-traceable calibration, and after calibration to verify whether different instruments measuring the same object provide results consistent within the expected uncertainty limits. This paper describes the activities and results of the first two phases of LCE-2: the SI-traceable radiometric calibration and indoor intercomparison, the results of outdoor experiment are presented in a related paper of the same journal issue. The indoor experiment of the LCE-2 has proven that uniform calibration just before the use of radiometers is highly effective. Distinct radiometers from different manufacturers operated by different scientists can yield quite close radiance and irradiance results (standard deviation s < 1%) under defined conditions. This holds when measuring stable lamp-based targets under stationary laboratory conditions with all the radiometers uniformly calibrated against the same standards just prior to the experiment. In addition, some unification of measurement and data processing must be settled. Uncertainty of radiance and irradiance measurement under these conditions largely consists of the sensor’s calibration uncertainty and of the spread of results obtained by individual sensors measuring the same object.

[1] Within the Radiance in a Dynamic Ocean (RaDyO) program, we have created and deployed a high dynamic range camera that can resolve the full spherical radiance distribution at the ocean surface and at depth. We present here the first results from deployments of the camera in near-surface water in eutrophic, mesotropic, and oligotropic environments. The instrument resolves the dynamics and fine structure of both the downwelling and upwelling radiance distribution and its variation with depth in these optically diverse water types. The various irradiances (E d , E u , E o , E ou , and E od ) are computed by integration. The distribution functions (e.g., the average cosines) are computed directly, as are the various diffuse attenuation coefficients. The fully specified radiance field therefore provides all the pertinent information to derive not only all of the apparent optical properties but, in principle, the inherent optical properties such as the absorption coefficient and the phase function as well. Comparison of the measured radiance field to independent measurements has shown very good agreement.

Original[1] Optical variability occurs in the near-surface and upper ocean on very short time and space scales (e.g., milliseconds and millimeters and less) as well as greater scales. This variability is caused by solar, meteorological, and other physical forcing as well as biological and chemical processes that affect optical properties and their distributions, which in turn control the propagation of light across the air-sea interface and within the

Rapid variations in the intensities of light are commonly observed in profiles of downwelling plane irradiance in the ocean. These fluctuations are often treated as noise and filtered out. Here an effort is made to extract the pertinent statistics to quantify the light field fluctuations from vertical profiles of irradiance measured under clear skies. The irradiance data are collected in oceanic and coastal waters using a traditional free-fall downwelling plane irradiance sensor. The irradiance profiles are transformed into timefrequency domain with a wavelet technique. Two signatures including the dominant frequency (<3.5 Hz) and the coefficient of variation of irradiance fluctuations along the water column are identified from the variance spectrum. Both the dominant frequency and the amplitude decrease as the inverse square root of depth, consistent with simple models of wave focusing and data from other studies. Mechanisms contributing to the observed variations and the observational uncertainties are discussed.