Archaeological investigations of the Colline Metallifere district (Southern Tuscany, Italy) have highlighted several Medieval sites located close to the main Cu-Pb-Fe (Ag) ore occurrences. This study is focused on the investigation of late-medieval slags from Cugnano and Montieri sites using both geochemical and mineralogical methods to understand slag heterogeneities as result of ore differences and technological processes. Matte-rich slags present in both sites (with abundant matte ± speiss and frequent relict phases) represent waste products related to primary sulphide ore smelting to obtain a raw lead bullion. The distribution of slags between the Ca-rich or Fe-rich dominant composition, and the consequent mineralogy, are tracers of the different ore–gangue association that occurred in the two sites. Silver is present only in very small matte-rich slags and ores enclosed within the mortar of the Montieri site; wastes derived from silver-rich mineral charges were probably crushed for the recovery of silver. Matte-poor slags found at Montieri represent a second smelting; raw lead bullion obtained from matte slags (both Fe- and Ca-rich) was probably re-smelted, adding silica and Al2O3-phase-rich fluxes, under more oxidizing conditions to reduce metal impurities. This second step was probably employed for Zn-rich lead ores; this process helped to segregate zinc within slags and improve the quality of the metal.

Dolia are large pottery containers used in Roman times for the storage and fermentation of wine. They were produced in specialized pottery workshops (figlinae) and were typically marked with specific epigraphical stamps, which represent a major tool to unravel their provenance and trade. In this work we present the preliminary results of a study of two dolia defossa, recently found at San Giovanni (Portoferraio, island of Elba, Italy) during 2012–2014 archaeological excavations in a Roman farm (late 2nd cent. BC-1st cent. AD), devoted to wine production and probably constituting the antecedent archaeological phase of the adjacent “Villa delle Grotte”. Based on archaeological (epigraphic) evidence, five different production areas have been hypothesized: 1) Elba island, where the dolia have been found; 2) the municipal figlinae in the Pisa territory; 3) the middle catchment of the Tiber river (central Latium) where “urban” figlinae occurred; 4) the figlinae of Minturno (southern Latium), a locality known both for wine production and exportation and for the presence of ancient figlinae; 5) the municipal figlinae in the Volterra territory. Archaeometric analysis of tempering agents intentionally added to the clay for the manufacturing of the dolia, particularly magmatic lithic fragments and clinopyroxene crystals, allowed us to suggest that the watershed of the central Tiber Valley - including different volcanic centres belonging to both Tuscany Magmatic Province (Monti Cimini) and Roman Magmatic Province (Monti Vulsini and Vico volcano) - could have been the most likely sites of production of the dolia found at San Giovanni. Alternatively, the site of Minturno (southern Latium) could be proposed

The material characterization of nineteenth-century artifacts is of great interest, due both to the breakthrough technological advances and to the unprecedented spread of forgeries of antiquities which took place in that period. However, this type of artifacts has been largely overlooked in the past. In this paper we present the compositional analysis of gold jewels by the Castellani, one of the most important families of goldsmiths in nineteenth-century Europe. The use of a portable micro-XRF spectrometer, specifically developed for jewellery analysis at the Centro Nacional de Aceleradores (Seville), allowed us to analyse, in a completely non-invasive way, the alloys, joining techniques and surface treatments of the jewels of the Castellani collection at the National Etruscan Museum of Villa Giulia in Rome. The addition to the spectrometer of a second X-rays detector with a zinc filter allowed us to check the possible presence of low amounts of cadmium, a metal added to gold soldering only from the nineteenth century and often used in authenticity studies. Moreover, the relative intensities of the Au X-ray lines were studied in order to check non-invasively the presence of surface enrichments in gold.

The so‐called Leman Album comprises over 90 designs for woven silks drawn and coloured in the early 18th century by James Leman, a designer and weaver operating in Spitalfields, East London. The designs are characterised by a very broad palette, which was investigated at the Victoria and Albert Museum using exclusively non‐invasive techniques. Notably, a bright and vibrant orange material was very popular with Leman, who used it extensively. X‐ray fluorescence tests showed that arsenic and sulfur were the predominant elements in the orange areas. A mixture of bright red, orange, and yellow particles could be seen under high magnification. These different types of particles were identified by Raman spectroscopy as arsenic sulfide glasses, that is artificial materials used as substitutes for naturally occurring pigments such as orpiment and realgar. In a few cases, a small amount of mineral orpiment was also detected. Such an extensive use of this artificial pigment is not commonly recorded in the literature. Because in a few of the handwritten comments that Leman made on the reverse of his designs he clearly stated “the orange colour to be gold,” we can reasonably hypothesise that this orange pigment was used for the parts that were intended to be woven with gilded metal threads. Textile designs made by other pattern‐makers working in Spitalfields in the same period as Leman were also analysed for comparison. Arsenic sulfide glass was detected in most of the orange areas, confirming that this material was certainly popular amongst silk designers of 18th‐century London.