The goal of this work is to introduce a coherent theory of the counterintuitive phenomena of dynamical destabilization under the action of dissipation. While the existence of one class of dissipation-induced instabilities was known to Sir Thomson ͑Lord Kelvin͒, it was not realized until recently that there is another major type of these phenomena hinted at by one of Merkin's theorems; in fact, these two cases exhaust all the generic possibilities. The theory grounded on the Thomson-Tait-Chetayev and Merkin theorems and on the geometric understanding introduced in this paper leads to the conclusion that ubiquitous dissipation is one of the paramount mechanisms by which instabilities develop in nature. Along with a historical review, the main theoretical achievements are put in a general context, thus unifying the current knowledge in this area and the multitude of relevant physical problems scattered over a vast literature. This general view also highlights the striking connection to various areas of mathematics. To appeal to the reader's intuition and experience, a large number of motivating examples are provided. The paper contains some new unpublished results and insights, and, finally, open questions are formulated to provide an impetus for future studies. While this review focuses on the finite-dimensional case, where the theory is relatively complete, a brief discussion of the current state of knowledge in the infinite-dimensional case, typified by partial differential equations, is also given.

In this work we present an experimental study of deviations from the classical Landau-Levich law in the problem of dip coating. Among the examined causes leading to deviations are the nature of the liquid-gas and liquid-solid interfaces. The thickness of the coating film created by withdrawal of a plate from a bath was measured gravimetrically over a wide range of capillary numbers for both smooth and well-characterized rough substrates, and for clean and surfactant interface cases. In view of the dependence of the lifetime of a film on the type of liquid and substrate, and liquid-gas and liquid-solid interfaces, we characterized the range of measurability of the film thickness in the parameter space defined by the withdrawal capillary number, the surfactant concentration, and substrate roughness size. We then study experimentally the effect of a film thickening due to the presence of surfactants. Our recent theory based on a purely hydrodynamic role of the surface active substance suggests that there is a sorption-controlled coating regime in which Marangoni effects should lead to film thinning. However, our experiments conducted in this regime demonstrate film thickening, calling into question the conventional wisdom, which is that Marangoni stresses ͑as accounted by the conventional interfacial boundary conditions͒ lead to film thickening. Next we examine the effect of well-characterized substrate roughness on the coated film thickness, which also reveals its influence on wetting-related processes and an effective boundary condition at the wall. In particular, it is found that roughness results in a significant thickening of the film relative to that on a smooth substrate and a different power of capillary number than the classical Landau-Levich law.

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In this work we study the classical Landau-Levich problem of dip-coating. While in the clean interface case and in the limit of low capillary numbers it admits an asymptotic solution, its full study has not been conducted. With the help of an efficient numerical algorithm, based on a boundary-integral formulation and the appropriate set of interfacial and inflow boundary conditions, we first study the film thickness behaviour for a clean interface problem. Next, the same algorithm allows us to investigate the response of this system to the presence of soluble surface active matter, which leads to clarification of its role in the flow dynamics. The main conclusion is that pure hydrodynamical modelling of surfactant effects predicts film thinning and therefore is not sufficient to explain the film thickening observed in many experiments.