Abstract-The behavior of Wireless Sensor Networks (WSN) is nowadays widely analyzed. One of the most important issues is related to their energy consumption, as this has a major impact on the network lifetime. Another important application requirement is to ensure data sensing synchronization, which leads to additional energy consumption as a high number of messages is sent and received at each node. Our proposal consists in implementing a combined synchronization protocol based on the IEEE 1588 standard that was designed for wired networks and the PBS (Pairwise Broadcast Synchronization) protocol that was designed for sensor networks, as none of them is able to provide the needed synchronization accuracy for our application on its own. The main goals of our new synchronization protocol are: to ensure the accuracy of local clocks up to a tenth of a microsecond and to provide an important energy saving. Our results obtained using NS-2 (Network Simulator) show that the performance of our solution (IEEE 1588-PBS) matches our application requirements with regard to the synchronization, with a significant improvement in energy saving.

Well‐defined colloidal dispersions of vinyl alcohol–vinyl acetate copolymers (PVAs) with different degrees of hydrolysis (DH) were prepared by a coacervation technique. Colloidal particles in the size range 150–250 nm, with an acetate‐rich core and a hydrophilic PVA corona, were obtained using a combination of a hydrophobic PVA (PVA II) having an average DH ($\overline{DH}$) value of 43 mol% with a ‘blocky’ hydrophilic PVA (PVA I) with a $\overline{DH}$ value of 72 mol%. The core–shell structure of these particles was demonstrated using 1H NMR and using fluorescence‐labelled PVA I. The stabilization efficiency of PVA I and PVA II and their combination was examined for 1‐chlorobutane–water emulsions, as a ‘model solvent’ for vinyl chloride–water emulsions. Preliminary tests of vinyl chloride suspension polymerization confirmed the beneficial effect of PVA I and PVA II combinations as stabilizers on the granulometry and the porosity specifications of the poly(vinyl chloride) grains. Copyright © 2006 Society of Chemical Industry