Bekok River is one of the raw water resources for Batu Pahat treatment plants which supply treated water for domestic, institutional, commercial and industrial use. Due to soil characteristics and agricultural activities in the catchment area, pH of lower than 5.5 is common to the river, particularly in the stretch where the water intake point is located. However, at times, Bekok River registered low pH of less than 3.5 and hence caused problems to the treatment plants. The cost to neutralise the water increased and treatment scheduling became more complicated. A preliminary laboratory scale study has been conducted to determine the viability of using an open limestone channel as an in-situ pH treatment in the river. Two sets of experiments using synthetic and actual raw waters with various sizes and amount of limestone were carried out. Results indicate the viability of the process. Depending on the initial pH and acidity of the raw water, the pH can rise to 6.0 within 30 minutes of contact time. The amount and size of limestone was found to play an important role in minimising the contact time.
Radiation exposure related human hazards and environmental pollution caused by the natural and manmade radioactive materials needs inhibition. An accurate evaluation of the radiation levels and geochemical factors of soil play a vital role. In this perception, γ-ray spectroscopy with NaI (Tl) luminescence detector was used to assess the natural radioactivity level and associated radiological risk due to contaminated surface soil (33 samples) collected from the Waist province of Iraq. Compared to the stipulated global average, about 64% and 15% of the samples showed higher radioactivity concentration of 226Ra and 40K, respectively, whereas for 232Th it was lower. Furthermore, the statistical guides of the geo-accumulation and contamination factors were used to calculate the pollution levels in the soil samples. The geochemical factors for some polluting heavy metals (Ge, Se, Ag, Sn, Sb, Te, I, Ce, Hf, W, Hg, Ti, and Bi) in the samples revealed wide variation. The contamination factor and I-Geo-accumulation catalogues of the samples exhibited the pollution level fluctuations from very high (Hg of 1.88 ppm) to very low (W of 1.33 ppm, U of 1.87 ppm, Sn of 3.8 ppm, Sb of 2.99 ppm, Ti of 0.66 ppm and Ag of 1.92 ppm, Bi of 1 ppm) to moderate Se of 0.53 ppm, Hf of 1.81 ppm and I of 3.19 ppm). It was asserted that the observed intense adsorption of some specific metals on the surface soils was due to the natural sources in the clays and heavy minerals originated from the carbonates. Such heavy elements could move into the minerals structure of the surface soils from the anthropogenic urban wastes, agricultural and industrial activities.
Kufa, considered one of the important cities in Iraq, is facing a rapid increase in population proportion and urban development in buildings and industry. Therefore, the concentration of several hazardous heavy metals is the main focus of this study. It presents the distribution and Estimation of heavy metals in urban lands in the Kufa area as an environmental geochemical study. Twenty samples of urban surface soils were collected in many sites to determine concentrations, distribution, and contamination of elements Cu, Zn, Co, Ni, Th, U, Pb, Hf, Nb, and Fe. The mean concentrations of heavy metals were compared with the local studies, UCC guidelines, and the world reference. To distinguish anthropogenic pollution, EF and Igeo guides were calculated. The obtained results established that contamination in Kufa soil land was slightly polluted by U (2.83ppm) and Nb (10.81ppm) and moderately polluted by Pb (31.7ppm) and Hf (9.75ppm). The research revealed that the reason for the elevation in the lead in the Kufa soil is that it often suffers from severe vehicle overcrowding during religious occasions.
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