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As the criterion used by archaeologists for determining early white porcelain is quite ambiguous, the origin of Chinese white porcelain remains a point of disagreement. In this study, we systematically investigate 61 typical Xing porcelains of the late Northern dynasties to the early Sui dynasty (550-600 CE) using spectrophotometer, X-ray fluorescence (XRF), scanning electron microscopy (SEM), and X-ray powder diffraction (XRD), and analyze the differences between early white porcelain and celadon of Xing kiln in terms of their whiteness and raw materials characteristic. The results show that early white porcelain is a new type of ware that differs from celadon, which can be distinguished by whiteness, with a whiteness greater than 8% being early white porcelain and a whiteness less than 8% being celadon. It is assumed that the ancient potters created the whiter wares based on celadon by improving the glaze and selecting new raw materials for the body, but the production of this type of ware was short lived and subsequently refined in the Sui dynasty (581-618 CE) owing to the limited improvement in whiteness.