The electron transfer capacities (ETCs) of soil humic substances (HSs) are linked to the type and abundance of redox-active functional moieties in their structure. Natural temperature can affect the chemical structure of natural organic matter by regulating their oxidative transformation and degradation in soil. However, it is unclear if there is a direct correlation between ETC of soil HS and mean annual temperature. In this study, we assess the response of the electron-accepting and -donating capacities (EAC and EDC) of soil HSs to temperature by analyzing HSs extracted from soil set along glacial-interglacial cycles through loess-palaeosol sequences and along natural temperature gradients through latitude and altitude transects. We show that the EAC and EDC of soil HSs increase and decrease, respectively, with increasing temperature. Increased temperature facilitates the prevalence of oxidative degradation and transformation of HS in soils, thus potentially promoting the preferentially oxidative degradation of phenol moieties of HS or the oxidative transformation of electron-donating phenol moieties to electron-accepting quinone moieties in the HS structure. Consequently, the EAC and EDC of HSs in soil increase and decrease, respectively. The results of this study could help to understand biogeochemical processes, wherein the redox functionality of soil organic matter is involved in the context of increasing temperature.

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The confounding effects of step change invalidate the stationarity assumption of commonly used trend analysis methods such as the Mann-Kendall test technique, so previous studies have failed to explain inconsistencies between detected trends and observed large precipitation anomalies. The objectives of this study were to (1) formulate a trend analysis approach that considers nonstationarity due to step changes, (2) use this approach to detect trends and extreme occurrences of precipitation in a mid-latitude Eurasian steppe watershed in North China, and (3) examine how runoff responds to precipitation trends in the study watershed. Our results indicate that annual precipitation underwent a marginal step jump around 1995. The significant annual downward trend after 1994 was primarily due to a decrease in summer rainfall; other seasons exhibited no significant precipitation trends. At a monthly scale, July rainfall after 1994 exhibited a significant downward trend, whereas precipitation in other months had no trend. The percentage of wet days also underwent a step jump around 1994 following a significant decreasing trend, although the precipitation intensity exhibited neither a step change nor any significant trend. However, both low-frequency and high-frequency precipitation events in the study watershed occurred more often after than before 1994; probably as either a result or an indicator of climate change. In response to these precipitation changes, the study watershed had distinctly different precipitation-runoff relationships for observed annual precipitations of less than 300 mm, between 300 and 400 mm, and greater than 400 mm.