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Bis maleimide-terminated poly-L-lactide (M-PLLA-M) and bis furan-terminated poly-D-lactide (F-PDLA-F) were synthesized by isocyanate coupling reactions of mono maleimide-terminated PLLA (M-PLLA) and mono furanterminated PDLA (F-PDLA) that had been prepared by the ordinary ring opening polymerization of L-and D-lactides with N-(2-hydroxyethyl)-maleimide and furfurylamine as the initiators, respectively. Both the M-PLLA-M and F-PDLA-F were dissolved in CH2Cl2 in 1 : 1 ratio and subjected to the ordinary electrospinning where the initial polymer concentration was increased up to 20 wt% because of the prepolymer state of the solute and the fiber diameter could be retained in nanometer to submicron size. The molecular weight of the polymers was found to have increased from 1.0 × 10 4 to 2.5 and 4.5 × 10 4 after the electrospinning and post annealing, respectively, due to the spontaneous chain extension taking place by the terminal Diels-Alder reaction of M-PLLA-M and F-PDLA-F to form a stereoblock polylactide. The as-spun fibers were amorphous or partially semi-crystalline, whereas the annealed fibers become fully crystalline due to the formation of the stereocomplex showing a melting temperature above 200°C.

Tanabe bay is a small embayment connected directly to the Pacific Ocean to the south, whereas frequently suffers from harmful algal blooms due to sewage effluent and the local aquaculture industry. For preserving the ecosystem in the bay, it is necessary to understand an oceanic structure in the bay along with water exchange at the bay entrance. We thus conduct a comprehensive investigation consisting of a shipboard measurement, a season-long platform observation, and a triply nested high-resolution ocean modeling. The water exchange at the bay mouth is largely affected by semi-diurnal tidal currents and episodic subtidal intrusion of the offshore water controlled by mesoscale circulations.

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