A procedure for the synthesis of monodisperse spherical mesoporous silica particles (MSMSPs) via the controlled coagulation of silica/surfactant clusters into spherical aggregates with mean diameters of 250-1500 nm has been developed. The synthesis is fast (taking less than 1 h) because identical clusters are simultaneously formed in the reaction mixture. The results of microscopic, x-ray diffraction, adsorption and optical measurements allowed us to conclude that the clusters are ∼15 nm in size and have hexagonally packed cylindrical pore channels. The channel diameters in MSMSPs obtained with cethyltrimethylammonium bromide and decyltrimethylammonium bromide as structure-directing agents were 3.1 ± 0.15 and 2.3 ± 0.12 nm, respectively. The specific surface area and the pore volume of MSMSP were, depending on synthesis conditions, 480-1095 m(2) g(-1) and 0.50-0.65 cm(3) g(-1). The MSMSP were used to grow opal-like photonic-crystal films possessing a hierarchical macro-mesoporous structure, with pores within and between the particles. A selective filling of mesopore channels with glycerol, based on the difference between the capillary pressures in macro- and mesopores, was demonstrated. It is shown that this approach makes it possible to control the photonic bandgap position in mesoporous opal films by varying the degree of mesopore filling with glycerol.
We have analyzed a data set taken over 2.76 years live time with the Baikal neutrino telescope NT200. The goal of the analysis is to search for neutrinos from dark matter annihilation in the center of the Sun. Apart from the conventional annihilation channels bb, W + W − and τ + τ − we consider also the annihilation of dark matter particles into monochromatic neutrinos. From the absence of any excess of events from the direction of the Sun over the expected background, we derive 90% upper limits on the fluxes of muons and muon neutrinos from the Sun, as well as on the elastic cross sections of dark matter scattering on protons.
The Prototyping phase of the BAIKAL-GVD project has been started in April 2011 with the deployment of a three string engineering array which comprises all basic elements and systems of the Gigaton Volume Detector (GVD) in Lake Baikal. In April 2012 the version of engineering array which comprises the first full-scale string of the GVD demonstration cluster has been deployed and operated during 2012. The first stage of the GVD demonstration cluster which consists of three strings is deployed in April 2013. We review the Prototyping phase of the BAIKAL-GVD project and describe the configuration and design of the 2013 engineering array.
Baikal-GVD is a next generation, kilometer-scale neutrino telescope under construction in Lake Baikal. It is designed to detect astrophysical neutrino fluxes at energies from a few TeV up to 100 PeV. GVD is formed by multi-megaton subarrays (clusters). The array construction was started in 2015 by deployment of a reduced-size demonstration cluster named "Dubna" . The first cluster in it's baseline configuration was deployed in 2016, the second in 2017 and the third in 2018. The full-scale GVD will be an array of ∼10.000 light sensors with an instrumented volume about of 2 cubic km. The first phase (GVD-1) is planned to be completed by 2020-2021. It will comprise 8 clusters with 2304 light sensors in total. We describe the design of Baikal-GVD and present selected results obtained in 2015 -2017.
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