No abstract

1998 thermodynamic functions, thermochemistry thermodynamic functions, thermochemistry E 3000 -020Thermodynamic Investigations of Liquid Gallium-Cadmium Alloys.-The activity of Cd in liquid Ga-Cd alloys in the 723-851 K range is determined by an electrochemical technique using LiCl-KCl + 5 wt.% CdCl 2 as molten salt electrolyte. The system exhibits a strong positive deviation from Raoult's law and does not follow the regular solution model. The thermodynamic data cannot be interpreted according to the Darken's quadratic formalism. The system shows poor stability in the 0.25 ≤ x Cd ≤ 0.45 composition range indicating a tendency for immiscibility in this composition range. -(SHAMSUDDIN, M.; SINGH, S. B.; NASAR, A.; Thermochim.