We investigate the electrical conductance and thermopower of a quantum dot tunnel coupled to external leads described by an extension of the Anderson impurity model which takes into account the assisted hopping processes, i.e., the occupancy-dependence of the tunneling amplitudes. We provide analytical understanding based on scaling arguments and the Schrieffer-Wolff transformation, corroborated by detailed numerical calculations using the numerical renormalization group method. The assisted hopping modifies the coupling to the two-particle state, which shifts the Kondo exchange coupling constant and exponentially reduces or enhances the Kondo temperature, breaks the particlehole symmetry, and strongly affects the thermopower. We discuss the gatevoltage and temperature dependence of the transport properties in various regimes. For a particular value of the assisted hopping parameter we find peculiar discontinuous behaviour in the mixed-valence regime. Near this value, we find very high Seebeck coefficient. We show that, quite generally, the thermopower is a highly sensitive probe of assisted hopping and Kondo correlations.

We present studies of thermal entanglement of a three-spin system in triangular symmetry. Spin correlations are described within an effective Heisenberg Hamiltonian, derived from the Hubbard Hamiltonian, with super-exchange couplings modulated by an effective electric field. Additionally a homogenous magnetic field is applied to completely break the degeneracy of the system. We show that entanglement is generated in the subspace of doublet states with different pairwise spin correlations for the ground and excited states. At low temperatures thermal mixing between the doublets with the same spin destroys entanglement, however one can observe its restoration at higher temperatures due to the mixing of the states with an opposite spin orientation or with quadruplets (unentangled states) always destroys entanglement. Pairwise entanglement is quantified using concurrence for which analytical formulae are derived in various thermal mixing scenarios. The electric field plays a specific role -it breaks the symmetry of the system and changes spin correlations. Rotating the electric field can create maximally entangled qubit pairs together with a separate spin (monogamy) that survives in a relatively wide temperature range providing robust pairwise entanglement generation at elevated temperatures.

Abstract. We consider a triple quantum dot system in a triangular geometry with one of the dots connected to metallic leads. Using Wilson's numerical renormalization group method, we investigate quantum entanglement and its relation to the thermodynamic and transport properties in the regime where each of the dots is singly occupied on average, but with non-negligible charge fluctuations. It is shown that even in the regime of significant charge fluctuations the formation of the Kondo singlets induces switching between separable and perfectly entangled states. The quantum phase transition between unentangled and entangled states is analyzed quantitatively and the corresponding phase diagram is explained by exactly solvable spin model. In the framework of an effective model we also explain smearing of the entanglement transition for cases when the symmetry of the triple quantum dot system is relaxed.