Quantum cascade lasers(1,2) can be considered the primary achievement of electronic band structure engineering, showing how artificial materials can be created through quantum design to have tailor-made properties that are otherwise non-existent in nature. Indeed, quantum cascade lasers can be used as powerful testing grounds of the fundamental physical parameters determined by their quantum nature, including the intrinsic linewidth of laser emission(3), which in such lasers is significantly affected by the optical and thermal photon number generated in the laser cavity. Here, we report experimental evidence of linewidth values approaching the quantum limit(4,5) in far-infrared quantum cascade lasers. Despite the broadening induced by thermal photons, the measured linewidth results narrower than that found in any other semiconductor laser to date. By performing noise measurements with unprecedented sensitivity levels, we highlight the key role of gain medium engineering(6) and demonstrate that properly designed semiconductor-heterostructure lasers can unveil the mechanisms underlying the laser-intrinsic phase noise, revealing the link between device properties and the quantum-limited linewidth

A comprehensive investigation of the frequency-noise spectral density of a free-running midinfrared quantum-cascade laser is presented for the first time. It provides direct evidence of the leveling of this noise down to a white-noise plateau, corresponding to an intrinsic linewidth of a few hundred hertz. The experiment is in agreement with the most recent theory on the fundamental mechanism of line broadening in quantum-cascade lasers, which provides a new insight into the Schawlow-Townes formula and predicts a narrowing beyond the limit set by the radiative lifetime of the upper level.

Radiocarbon ((14)C) concentrations at a 43 parts-per-quadrillion level are measured by using saturated-absorption cavity ringdown spectroscopy by exciting radiocarbon-dioxide ((14)C(16)O(2)) molecules at the 4.5 μm wavelength. The ultimate sensitivity limits of molecular trace gas sensing are pushed down to attobar pressures using a comb-assisted absorption spectroscopy setup. Such a result represents the lowest pressure ever detected for a gas of simple molecules. The unique sensitivity, the wide dynamic range, the compactness, and the relatively low cost of this table-top setup open new perspectives for ^{14}C-tracing applications, such as radiocarbon dating, biomedicine, or environmental and earth sciences. The detection of other very rare molecules can be pursued as well thanks to the wide and continuous mid-IR spectral coverage of the described setup.

We report on the engineering of broadband quantum cascade lasers (QCLs) emitting at Terahertz (THz) frequencies, which exploit a heterogeneous active region scheme and have a current density dynamic range (J dr ) of 3.2, significantly larger than the state of the art, over a 1.3THz bandwidth. We demonstrate that the devised broadband lasers operate as THz optical frequency comb synthesizers in continuous-wave, with a maximum optical output power of 4 mW (0.73mW in the comb regime). Measurement of the intermode beatnote map reveals a clear dispersion-compensated frequency comb regime extending over a continuous 106 mA current range (current density dynamic range of 1.24), significantly larger than the state of the art reported under similar geometries, with a corresponding emission bandwidth of ≈ 1.05 THz and a stable and narrow (4.15 KHz) beatnote detected with a signal-to-noise ratio of 34 dB. Analysis of the electrical and thermal beatnote tuning reveals a current-tuning coefficient ranging between 5 MHz/mA and 2.1 MHz/mA and a temperature-tuning coefficient of -4 MHz/K. The ability to tune the THz QCL combs over their full dynamic range by temperature and current paves the way for their use as a powerful spectroscopy tool that can provide broad frequency coverage combined with high precision spectral accuracy.The terahertz (THz) region of the electromagnetic spectrum, conventionally covering the frequency range from 0.1 THz to 10 THz, plays an important role for applications [1]. Specifically, sensing, high-resolution spectroscopy [2][3][4], and metrology [5] have an enormous potential in this spectral region since many chemical compounds and simple molecules possess rotational and vibrational resonances at THz frequencies [1-3]. However, rotational transitions have natural linewidths of a

We report on a novel approach to cavity ring-down spectroscopy with the sample gas in saturated-absorption regime. This technique allows us to decouple and simultaneously retrieve the empty-cavity background and absorption signal, by means of a theoretical model that we developed and tested. The high sensitivity and frequency precision for spectroscopic applications are exploited to measure, for the first time, the hyperfine structure of an excited vibrational state of 17O12C16O in natural abundance with an accuracy of a few parts in 10{-11}.