a b s t r a c tWe discuss two methods by which high porosity silica aerogels can be engineered to exhibit global anisotropy. First, anisotropy can be introduced with axial strain (i.e. axial compression). In addition, intrinsic anisotropy can result during growth and drying stages and, suitably controlled, it can be correlated with preferential radial shrinkage in cylindrical samples. We have performed small angle X-ray scattering (SAXS) to characterize these two types of anisotropy. We show that global anisotropy originating from either strain or shrinkage leads to optical birefringence and that optical cross-polarization studies are a useful characterization of the uniformity of the imposed global anisotropy.
We have performed Small Angle X-ray Scattering (SAXS) on uniaxially strained
aerogels and measured the strain-induced structural anisotropy. We use a model
to connect our SAXS results to anisotropy of the 3He quasiparticle mean free
path in aerogel.Comment: 2 pages, 2 figures, accepted for publication in the proceedings of
the 24th Low Temperature Physics Conferenc
It may be possible to stabilize new superfluid phases of 3 He with anisotropic silica aerogels. We discuss two methods that introduce anisotropy in the aerogel on length scales relevant to superfluid 3 He. First, anisotropy can be induced with uniaxial strain. A second method generates anisotropy during the growth and drying stages. We have grown cylindrical ∼98% aerogels with anisotropy indicated by preferential radial shrinkage after supercritical drying and find that this shrinkage correlates with small angle x-ray scattering (SAXS). The growth-induced anisotropy was found to be ∼90 • out of phase relative to that induced by strain. This has implications for the possible stabilization of superfluid phases with specific symmetry.
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