We present an analysis of the mid-infrared (MIR) and optical properties of type 1 (broad-line) quasars detected by the Spitzer Space Telescope. The MIR color-redshift relation is characterized to z $ 3, with predictions to z ¼ 7. We demonstrate how combining MIR and optical colors can yield even more efficient selection of active galactic nuclei (AGNs) than MIR or optical colors alone. Composite spectral energy distributions (SEDs) are constructed for 259 quasars with both Sloan Digital Sky Survey and Spitzer photometry, supplemented by near-IR, GALEX, VLA, and ROSAT data, where available. We discuss how the spectral diversity of quasars influences the determination of bolometric luminosities and accretion rates; assuming the mean SED can lead to errors as large as 50% for individual quasars when inferring a bolometric luminosity from an optical luminosity. Finally, we show that careful consideration of the shape of the mean quasar SED and its redshift dependence leads to a lower estimate of the fraction of reddened /obscured AGNs missed by optical surveys as compared to estimates derived from a single mean MIR to optical flux ratio.

We present a catalog of 5039 broad absorption line (BAL) quasars (QSOs) in the Sloan Digital Sky Survey (SDSS) Data Release 5 (DR5) QSO catalog that have absorption troughs covering a continuous velocity range ≥ 2000 km s −1 . We have fit ultraviolet (UV) continua and line emission in each case, enabling us to report common diagnostics of BAL strengths and velocities in the range −25, 000 to 0 km s −1 for Si IV λ1400, C IV λ1549, Al III λ1857, and Mg II λ2799. We calculate these diagnostics using the spectrum listed in the DR5 QSO catalog, and also for spectra from additional SDSS observing epochs when available. In cases where BAL QSOs have been observed with Chandra or XMM-Newton, we report the X-ray monochromatic luminosities of these sources.We confirm and extend previous findings that BAL QSOs are more strongly reddened in the rest-frame UV than non-BAL QSOs and that BAL QSOs are -2relatively X-ray weak compared to non-BAL QSOs. The observed BAL fraction is dependent on the spectral signal-to-noise (S/N); for higher-S/N sources, we find an observed BAL fraction of ≈15%. BAL QSOs show a similar Baldwin effect as for non-BAL QSOs, in that their C IV emission equivalent widths decrease with increasing continuum luminosity. However, BAL QSOs have weaker C IV emission in general than do non-BAL QSOs. Sources with higher UV luminosities are more likely to have higher-velocity outflows, and the BAL outflow velocity and UV absorption strength are correlated with relative X-ray weakness. These results are in qualitative agreement with models that depend on strong X-ray absorption to shield the outflow from over-ionization and enable radiative acceleration. In a scenario in which BAL trough shapes are primarily determined by outflow geometry, observed differences in Si IV and C IV trough shapes would suggest that some outflows have ion-dependent structure.

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