A CuInSe2 (CIS) bulk single crystal grown by the directional freezing method from the melt at 1250°C shows superior crystal quality, as evidenced by its (p-type) electrical properties. Photoluminescence at 1.5 K shows a strong and well resolved spectrum with fine structures never before observed from this compound. Free exciton emission exhibits a doublet structure which can either be described as a splitting due to the uniaxial crystal field or as a polariton. The energy gap of the CIS semiconductor as determined from the temperature dependence of the free exciton line is 1.058 eV. Two moderate free-to-bound transitions are assigned to VCu and CuIn acceptors. A weak PL peak corresponding to a deep level is interpreted as arising from the Sei acceptor. Strong phonon replicas are also observed for the first time in a CIS bulk single crystal. The phonon wavelength of 218–237 cm-1 is in good agreement with the reported Raman result of 233 cm-1 for the LO phonon.
We have used a scanning YBa2Cu3O7 superconducting quantum interference device (SQUID) at 77 K to image currents in room-temperature integrated circuits. We acquired magnetic field data and used an inversion technique to convert the field data to a two-dimensional current density distribution, allowing us to locate current paths. With an applied current of 1 mA at 3 kHz, and a 150 μm separation between the sample and the SQUID, we found a spatial resolution of 50 μm in the converted current density images. This was about three times smaller than the SQUID–sample separation, i.e., three times better than the standard near-field microscopy limit, and about 10 times sharper than the raw magnetic field images.
We have used a high-T, scanning SQUID microscope to image semiconductor circuits operating in air at room temperature. Our microscope uses a commercially available 77 K refrigerator to cool a YBa2CuJ07d de SQUID. The system maintains vacuum isolation of the SQUID even when it is separated from a room-temperature sample by about 30 pm. When operated in this manner, the SQUID has a magnetic field sensitivity of 20 pTIdHz above 500 Hz. By inverting the magnetic field images to generate two-dimensional current density distributions, we localize current paths to within 5336 pm at SQUID-sample separations of 150 pm. We present images and discuss the spatial resolution obtained with this technique.
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