An experimental investigation of droplet generation by a plunging breaking wave is presented. In this work, simultaneous measurements of the wave crest profile evolution and of droplets ranging in radius down to 50 μm for a mechanically generated plunging breaker during many repeated breaking events in freshwater are performed. We find three distinct time zones of droplet production, first when the jet impacts the free surface upstream of the wave crest, second when the large air bubbles entrapped by the plunging jet impact reach the free surface and burst, and third when smaller bubbles burst upon reaching the free surface later in the breaking process. These subprocesses account for 22%, 44%, and 34%, respectively, of the average of 653 droplets produced per breaking event. The probability distributions of the ranges of large and small droplet radii are well represented by power law functions that intersect at a radius of 418 μm.