In this proceeding. the compositions of the T-30 turbine oil with liquid rubber. Co. Ni. Zn. Mg and Ba salts of the natural petroleum acids (NPA) boiling in the range 220-340 o C and nitro compounds which are produced on the basis of C 14 H 28 α-olefi ns have been investigated in different ratio and contents as metalworking fl uids (MWF). The physical and chemical properties of the produced compositions have been studied. and the morphology of inhibited carbon steel surface was analyzed and characterized by using Fourier transform infrared (FTIR) and scanning electron microscopy (SEM) techniques. The effect of the temperature on the inhibition effi ciency and thermodynamic parameters have also been reported. The thermal analyzer was used for the thermogravimetric analysis (TG/DTA) of the prepared MWF. The experiments have been operated with different concentrations of the inhibitor on the steel plates in condensation and environment phases in the experiment chamber.
In the process, inorganic complexes of amidoamines obtained from the interaction of natural petroleum acid and oleic acids with diethylenetriamine have been developed and their effectiveness as inhibitor-bactericides has been investigated. The effect of the synthesized reagents on the kinetics of the corrosion process of steel and the activity of sulphate-reducing bacteria in 3% NaCl solution saturated with CO2 and in the biphasic water–isopropyl alcohol medium with H2S dissolved has been analyzed. The thermodynamic and kinetic parameters of the corrosion process were calculated. The adsorption of the complexes was investigated using the Langmuir isotherm and the correlation constant was determined. State of the metal surface was investigated by SEM method in CO2 and H2S media, with and without inhibitors, and the metal surface contact of complexes was studied by computer molecular simulation.
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