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Accelerator mass spectrometric radiocarbon measurements on benthic foraminifera shells, picked from samples on which concordant ages were obtained on the shells of two species of planktonic foraminifera, reveal that the age of deep water in the equatorial Atlantic during glacial time was 675±80 years (compared to today's age of 350 years) and that the age of deep water in the South China Sea was 1670±105 years (compared to today's value of 1600 years). These results demonstrate that the 1.3 to 1.5 times higher radiocarbon content of carbon in glacial surface waters of the Caribbean Sea reconstructed by Bard et al. [1990] was primarily the result of a higher global inventory of radiocarbon rather than a decrease in rate of mixing between surface and deep waters of the ocean. The results are also consistent with the conclusion by Boyle and Keigwin [1987] that the flow of North Atlantic Deep Water was considerably weakened during glacial time, allowing deep waters of Antarctic origin to push much further north into the Atlantic than they do today.

ABSTRACT.A new radiocarbon accelerator mass spectrometry (AMS) laboratory for carbon cycle studies has been established at the University of California, Irvine. The 0.5MV AMS system was installed in mid-2002 and has operated routinely since October of that year. This paper briefly describes the spectrometer and summarizes lessons learned during the first year of operation. In the process of setting up the system, we identified and largely suppressed a previously unreported 14 C AMS background: charge exchange tails from 14 N beams derived from nitrogen-containing molecular ions produced near the entrance of the accelerator.

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The radiocarbon content and stable isotope composition of soil carbonate are best described by a dynamic system in which isotopic reequilibration occurs as a result of recurrent dissolution and reprecipitation. Depth of water penetration into the soil profile, as well as soil age, determines the degree of carbonate isotope reequilibration. We measured δ13C, δ18O and radiocarbon content of gravel rinds and fine (<2 mm) carbonate in soils of 3 .different ages (1000, 3800, and 6300 14 C yr B.P.) to assess the degree to which they record and preserve a climatic signal. In soils developing in deposits independently dated at 3800 and 6300 radiocarbon yr B.P., carbonate radiocarbon content above 40 cm depth suggests continual dissolution and reprecipitation, presumably due to frequent wetting events. Between 40 and 90 cm depth, fine carbonate is dissolved and precipitated as rinds that are not redissolved subsequently. Below 90 cm depth in these soils, radiocarbon content indicates that inherited, fine carbonate undergoes little dissolution and reprecipitation. In the 3800- and 6300-yr-old soils, δ13C in rind and fine carbonate follows a decreasing trend with depth, apparently in equilibrium with modern soil gas, as predicted by a diffusive model for soil CO2. δ18O also decreases with depth due to greater evaporative enrichment above 50 cm depth. In contrast, carbonate isotopes in a 1000-yr-old deposit do not reflect modern conditions even in surficial horizons; this soil has not undergone significant pedogenesis. There appears to be a lag of at least 1000 but less than 3800 yr before carbonate inherited with parent material is modified by ambient climatic conditions. Although small amounts of carbonate are inherited with the parent material, the rate of pedogenic carbonate accumulation indicates that Ca is derived primarily from eolian and rainfall sources. A model describing carbonate input and radiocarbon decay suggests that fine carbonate below 90 cm is mostly detrital (inherited) and that carbonate rinds have been forming pedogenically at a constant rate since alluvial fans were deposited.