A previously described method, based on considerations of hard-sphere theory, is used for the simultaneous correlation of the coefficients of viscosity, selfdiffusion, and thermal conductivity for the n-alcohols, from methanol to n-decanol, in excellent agreement with experiment, over extended temperature and pressure ranges. Generalized correlations are given for the roughness factors and the characteristic volume. The overall average absolute deviations of the experimental viscosity, self-diffusion, and thermal conductivity measurements from those calculated by the correlation are 2.4, 2.6, and 2.0%, respectively. Since the proposed scheme is based on accurate density values, a Tait-type equation was also employed to correlate successfully the density of the n-alcohols. The overall average absolute deviation of the experimental density measurements from those calculated by the correlation is +0.05%.
New measurements of the viscosity of methanol, ethanol, l-propanol, and 1-butanol are presented. The measurements were performed in a vibrating-wire instrument and cover a temperature range of 290-340 K and pressures up to 30 MPa. The overall uncertainty in the reported data, confirmed by the measurement of the viscosity of water, is + 0.5 %. The high-pressure experimental results were correlated by a Tait-like equation. It was found that the isothermal viscosity data were satisfactorily correlated by such an equation.
A recently developed scheme, based on considerations of hard-sphere theory, is used for the simultaneous correlation of the coefficients of viscosity and thermal conductivity l'or the refrigerants RII, RI2, R22, R32. RI24, RI25, RI34a, R141b, and RI52a in excellent agreement with experiment, over extended temperature and pressure ranges. Values for the roughness factors and correlations for the characteristic volume are presented. The overall average absolute deviations of the experimental viscosity and thermal conductivity measurements from those calculated by the correlation are 2.1 and 2.3°/., respectively, over a temperature range from 200 to about 10 K below the critical temperature and a pressure range from saturation to about 40 MPa. Since the proposed scheme is based on recent and accurate density values, a Tait-type equation was also employed to correlate successfully the density of the refrigerants. The overall average absolute deviation of the experinaental density measurements from those calculated by the correlation is +0.08°/,,.
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