New magnetic forms of C60 have been identified which occur
in the rhombohedral polymer phase. The existence of previously
reported ferromagnetic rhombohedral C60 is confirmed. This
property has been shown to occur over a range of preparation
temperatures at 9 GPa. The structure is shown to be crystalline
in nature containing whole undamaged buckyballs. Formation of
radicals is most likely due to thermally activated shearing of
the bridging bond resulting in dangling bond formation. With
increasing temperatures this process occurs in great enough
numbers to trigger cage collapse and graphitization. The
magnetically strongest sample was formed at 800 K, and has a
saturated magnetization at 10 K, in fields above 3 kOe, of
0.045 emu g-1.
The complete spectrum of the double spinon excitation in the spin-Peierls system CuGeO 3 is mapped as a function of temperature for the first time. The spin dynamics of the lower boundary and the excitation continuum evolve quite differently. Moreover, the dimerization of the lattice produces a sharp excitation in the lower energy boundary at the edge of the Brillouin zone, as well as the well known spin-gap opening at the zone center. [S0031-9007(96)01457-3]
A continuum of magnetic states has been observed by neutron scattering from the spin-1 chain compound CsNiCl3 in its disordered gapped one-dimensional phase. Results using both triple-axis and time-of-flight spectrometers show that around the antiferromagnetic point Qc = pi, the continuum lies higher in energy than the Haldane gapped excitations. At 6 K the integrated intensity of the continuum is about 12(2)% of the total spectral weight. This result is considerably larger than the 1%-3% weight predicted by the nonlinear sigma model for the three-particle continuum.
Well-defined phonons with strong anomalous ͑upward͒ dispersion are observed by inelastic neutron scattering in liquid para-H 2 at a temperature of 15.7 K. The damping, being very small for the low-Q phonons, increases with wave vector Q, and only broad features are observed for Qտ1 Å Ϫ1 . This behavior is shown to deviate strongly from results of molecular simulations of a fully classical analogue using a realistic potential.
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