Sedimentary rocks examined by the Curiosity rover at Yellowknife Bay, Mars, were derived from sources that evolved from approximately average Martian crustal composition to one influenced by alkaline basalts. No evidence of chemical weathering is preserved indicating arid, possibly cold, paleoclimates and rapid erosion/deposition. Absence of predicted geochemical variations indicates that magnetite and phyllosilicates formed by diagenesis under low temperature, circum-neutral pH, rock-dominated aqueous conditions. High spatial resolution analyses of diagenetic features, including concretions, raised ridges and fractures, indicate they are composed of iron-and halogen-rich components, magnesium-iron-chlorine-rich components and hydrated calcium-sulfates, respectively. Composition of a cross-cutting dike-like feature is consistent with sedimentary intrusion. Geochemistry of these sedimentary rocks provides further evidence for diverse depositional and diagenetic sedimentary environments during the early history of Mars.Introduction: Shortly after leaving its landing site at Bradbury Landing in Gale crater, the Mars Science Laboratory Curiosity rover traversed to Yellowknife Bay (1), where it encountered a flat-lying, ~5.2 meter thick succession of weakly indurated clastic sedimentary rocks ranging from mudstones at the base to mainly sandstones at the top (2). Stratigraphic relationships and

No abstract

Gale crater, geological context of the rover traverse and samples studiedThe Curiosity rover landing site is located at -4.59° S, 137.44° E). Fig. S1a shows a portion of the THEMIS IR nighttime mosaic of Bradbury Rise. The landing site is marked by a black cross within the landing ellipse. It is located at a distal portion of the alluvial fan stretching below Peace Vallis on the northern rim of Gale crater.Mafic and light-toned igneous float rocks were initially observed by the Curiosity rover close to the Bradbury landing site from sol 1 to 55 in the Hummocky plain unit. After Curiosity left the fluvio-lacustrine deposit of Yellow Knife Bay (sol 55-326), it traversed back across the hummocky unit (Fig. S1b). An increasing number of light-toned rocks dominated by feldspars (porphyritic, felsic coarse-grained, felsic fine-grained) together with three groups of mafic rocks were observed along the traverse from sol 326 to sol 550. The mafic rocks are described in detail in Cousin et al. (2015) 43 and Sautter et al. (2014) 45 . The rocks selected for the present study are summarized in Table S1. Laser-Induced Breakdown Spectrometer (LIBS) spectraChemCam's laser-induced breakdown spectrometer (LIBS) uses a pulsed laser to ablate targets up to ≈ 7 m from the rover. The size of the laser interaction varies with distance, ranging from 350 µm at 1.5 m to 550 µm at 7 m 36 . The light emitted by the ablated plasma spark is collected by the same telescope used to transmit the laser beam, and is analyzed by three spectrometers which record the atomic emission spectrum over the ultraviolet (UV: 240.1-342.2nm), violet (VIO: 382.1-469.3 nm), and visible to near-infrared (VNIR: 474.0-906.5 nm) ranges 21, 22 . The ChemCam LIBS spectra consist of 6144 channels covering the above wavelength range in wavelength with typically several hundred emission peaks covering all of the major elements and many minor and trace elements.A typical ChemCam LIBS observation involves the analysis of multiple locations on the target: common geometries for LIBS observations are square grids (e.g. 3×3, 4×4) and

International audienceThe ChemCam instrument suite on the Mars Science Laboratory (MSL) rover Curiosity provides remote compositional information using the first laser-induced breakdown spectrometer (LIBS) on a planetary mission, and provides sample texture and morphology data using a remote micro-imager (RMI). Overall, ChemCam supports MSL with five capabilities: remote classification of rock and soil characteristics; quantitative elemental compositions including light elements like hydrogen and some elements to which LIBS is uniquely sensitive (e.g., Li, Be, Rb, Sr, Ba); remote removal of surface dust and depth profiling through surface coatings; context imaging; and passive spectroscopy over the 240-905 nm range. ChemCam is built in two sections: The mast unit, consisting of a laser, telescope, RMI, and associated electronics, resides on the rover's mast, and is described in a companion paper. ChemCam's body unit, which is mounted in the body of the rover, comprises an optical demultiplexer, three spectrometers, detectors, their coolers, and associated electronics and data handling logic. Additional instrument components include a 6 m optical fiber which transfers the LIBS light from the telescope to the body unit, and a set of onboard calibration targets. ChemCam was integrated and tested at Los Alamos National Laboratory where it also underwent LIBS calibration with 69 geological standards prior to integration with the rover. Post-integration testing used coordinated mast and instrument commands, including LIBS line scans on rock targets during system-level thermal-vacuum tests. In this paper we describe the body unit, optical fiber, and calibration targets, and the assembly, testing, and verification of the instrument prior to launch

The Curiosity rover has analyzed abundant light-toned fracture-fill material within the Yellowknife Bay sedimentary deposits. The ChemCam instrument, coupled with Mastcam and ChemCam/Remote Micro Imager images, was able to demonstrate that these fracture fills consist of calcium sulfate veins, many of which appear to be hydrated at a level expected for gypsum and bassanite. Anhydrite is locally present and is found in a location characterized by a nodular texture. An intricate assemblage of veins crosses the sediments, which were likely formed by precipitation from fluids circulating through fractures. The presence of veins throughout the entire~5 m thick Yellowknife Bay sediments suggests that this process occurred well after sedimentation and cementation/lithification of those sediments. The sulfur-rich fluids may have originated in previously precipitated sulfate-rich layers, either before the deposition of the Sheepbed mudstones or from unrelated units such as the sulfates at the base of Mount Sharp. The occurrence of these veins after the episodes of deposition of fluvial sediments at the surface suggests persistent aqueous activity in relatively nonacidic conditions.