We present a highly complete and reliable mid-infrared (MIR) colour selection of luminous active galactic nucleus (AGN) candidates using the 3.4, 4.6 and 12 µm bands of the Widefield Infrared Survey Explorer (WISE) survey. The MIR colour wedge was defined using the wide-angle Bright Ultrahard XMM-Newton survey (BUXS), one of the largest complete flux-limited samples of bright (f 4.5-10 keV > 6 × 10 −14 erg s −1 cm −2 ) 'ultrahard' (4.5-10 keV) X-ray-selected AGN to date. The BUXS includes 258 objects detected over a total sky area of 44.43 deg 2 of which 251 are spectroscopically identified and classified, with 145 being type 1 AGN and 106 type 2 AGN. Our technique is designed to select objects with red MIR power-law spectral energy distributions (SEDs) in the three shortest bands of WISE and properly accounts for the errors in the photometry and deviations of the MIR SEDs from a pure power-law. The completeness of the MIR selection is a strong function of luminosity. At L 2-10 keV > 10 44 erg s −1 , where the AGN is expected to dominate the MIR emission, 97.1 +2.2 −4.8 and 76.5 +13.3 −18.4 per cent of the BUXS type 1 and type 2 AGN, respectively, meet the selection. Our technique shows one of the highest reliability and efficiency of detection of the X-rayselected luminous AGN population with WISE amongst those in the literature. In the area covered by BUXS our selection identifies 2755 AGN candidates detected with signal-to-noise ratio ≥5 in the three shorter wavelength bands of WISE with 38.5 per cent having a detection at 2-10 keV X-ray energies. We also analysed the possibility of including the 22 µm WISE band to select AGN candidates, but neither the completeness nor the reliability of the selection improves. This is likely due to both the significantly shallower depth at 22 µm compared with the first three bands of WISE and star formation contributing to the 22 µm emission at the WISE 22 µm sensitivity.

Aims. Pointed observations with XMM-Newton provide the basis for creating catalogues of X-ray sources detected serendipitously in each field. This paper describes the creation and characteristics of the 2XMM catalogue. Methods. The 2XMM catalogue has been compiled from a new processing of the XMM-Newton EPIC camera data. The main features of the processing pipeline are described in detail. Results. The catalogue, the largest ever made at X-ray wavelengths, contains 246 897 detections drawn from 3491 public XMM-Newton observations over a 7-year interval, which relate to 191 870 unique sources. The catalogue fields cover a sky area of more than 500 deg 2 . The non-overlapping sky area is ∼360 deg 2 (∼1% of the sky) as many regions of the sky are observed more than once by XMM-Newton. The catalogue probes a large sky area at the flux limit where the bulk of the objects that contribute to the X-ray background lie and provides a major resource for generating large, well-defined X-ray selected source samples, studying the X-ray source population and identifying rare object types. The main characteristics of the catalogue are presented, including its photometric and astrometric properties

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