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Exploration of Geothermal resources is important from energy point of view. Western margin of volcanic Deccan traps, also known as Western Ghats, is characterized with the presence of numerous hot springs. The resistivity contrast for the geothermal reservoir rock and the surrounding host rock is significantly high in volcanic terrain which is the case of present study. In such cases the resistivity associated with geothermal reservoirs usually varies from <5 to 15 Ohm-m regardless of how high resistivity is outside the reservoir zone. Direct current (DC) resitivity method is proved to be more suitable method for delineation of groundwater reservoirs. The present work describes the results of electrical resistivity tomography survey carried out at four hot spring sites located at Unhavare (Khed), Tural, Rajwadi and Aravali villages of Chiplun taluk in Ratnagiri district of Maharashtra for delineation of the geothermal reservoirs and associated geological features like faults and fractures responsible for vertical movement of geothermal water with the sole purpose of harnessing geothermal energy. In addition to this, the present study is also aimed to delineate the groundwater reservoirs with normal temperature for exploration purpose to meet the local water supply demand. The interpreted results of the field data suggest the presence of two potential geothermal reservoirs at Unhavare (Khed) and one each at Tural and Aravali. Potential groundwater zones with normal temperature are also delineated for groundwater exploration at Rajwadi and Aravali sites.