) data set on the chemical composition of ambient aerosols collected from an urban location (Kanpur) in the Indo-Gangetic Plain (IGP) and suggests that the varying strength of the regional emission sources, boundary layer dynamics, and formation of secondary aerosols all contribute significantly to the temporal variability in the mass concentrations of elemental carbon (EC), organic carbon (OC), and water-soluble OC (WSOC). On average, carbonaceous aerosols contribute nearly one third of the PM 10 mass during winter, whereas their fractional mass is only ∼10% during summer. A three-to four-fold increase in the OC and K + concentrations during winter and a significant linear relation between them suggest biomass burning (wood fuel and agricultural waste) emission as a dominant source. The relatively high OC/EC ratio (average: 7.4 ± 3.5 for n = 66) also supports that emissions from biomass burning are overwhelming for the particulate OC in the IGP. The WSOC/OC ratios vary from 0.21 to 0.70 over the annual seasonal cycle with relatively high ratios in the summer, suggesting the significance of secondary organic aerosols. The long-range transport of mineral aerosols from Iran, Afghanistan, and the Thar Desert (western India) is pronounced during summer months. The temporal variability in the concentrations of selected inorganic constituents and neutralization of acidic species (SO 4 2− and NO 3 − ) by NH 4 + (dominant during winter) and Ca 2+ (in summer) reflect conspicuous changes in the source strength of anthropogenic emissions.Citation: Ram, K., M. M. Sarin, and S. N. Tripathi (2010), A 1 year record of carbonaceous aerosols from an urban site in the Indo-Gangetic Plain: Characterization, sources, and temporal variability,
We study the field equations of modified theories of gravity in which the lagrangian is a general function of the Ricci scalar and Ricci-squared terms in Palatini formalism. We show that the independent connection can be expressed as the Levi-Cività connection of an auxiliary metric which, in particular cases of interest, is related with the physical metric by means of a disformal transformation. This relation between physical and auxiliary metric boils down to a conformal transformation in the case of f (R) theories. We also show with explicit models that the inclusion of Ricci squared terms in the action can impose upper bounds on the accessible values of pressure and density, which might have important consequences for the early time cosmology and black hole formation scenarios. Our results indicate that the phenomenology of f (R, Rµν R µν ) theories is much richer than that of f (R) and f (Rµν R µν ) theories and that they also share some similarities with Bekenstein's relativistic theory of MOND.
We consider static spherically symmetric stellar configurations in Palatini theories of gravity in which the Lagrangian is an unspecified function of the form f (R, R µν R µν ). We obtain the Tolman-Oppenheimer-Volkov equations corresponding to this class of theories and show that they recover those of f (R) theories and General Relativity in the appropriate limits. We show that the exterior vacuum solutions are of Schwarzschild-de Sitter type and comment on the possible expected modifications, as compared to GR, of the interior solutions.
Abstract. Ground-based observations have insufficient spatial coverage to assess long-term human exposure to fine particulate matter (PM 2.5 ) at the global scale. Satellite remote sensing offers a promising approach to provide information on both short-and long-term exposure to PM 2.5 at local-toglobal scales, but there are limitations and outstanding questions about the accuracy and precision with which groundlevel aerosol mass concentrations can be inferred from satellite remote sensing alone. A key source of uncertainty is the global distribution of the relationship between annual average PM 2.5 and discontinuous satellite observations of columnar aerosol optical depth (AOD). We have initiated a global network of ground-level monitoring stations designed to evaluate and enhance satellite remote sensing estimates for application in health-effects research and risk assessment. This Surface PARTiculate mAtter Network (SPARTAN) includes a global federation of ground-level monitors of hourly PM 2.5 situated primarily in highly populated regions and collocated with existing ground-based sun photometers that measure AOD. The instruments, a three-wavelength nephelometer and impaction filter sampler for both PM 2.5 and PM 10 , are highly autonomous. Hourly PM 2.5 concentrations are inferred from the combination of weighed filters and nephelometer data. Data from existing networks were used to develop and evaluate network sampling characteristics. SPARTAN filters are analyzed for mass, black carbon, watersoluble ions, and metals. These measurements provide, in a variety of regions around the world, the key data required to evaluate and enhance satellite-based PM 2.5 estimates used for assessing the health effects of aerosols. Mean PM 2.5 concentrations across sites vary by more than 1 order of magnitude. Our initial measurements indicate that the ratio of AOD to ground-level PM 2.5 is driven temporally and spatially by the vertical profile in aerosol scattering. Spatially this ratio is also strongly influenced by the mass scattering efficiency.
[1] During a comprehensive aerosol field campaign as part of Indian Space Research Organization Geosphere Biosphere Programme (ISRO-GBP), aircraft measurements of vertical profiles of aerosol black carbon (BC) were made during winter, for the first time, at Kanpur (80°20 0 E and 26°26 0 N), an urban industrial location in Northern India. Two vertical profiling from the same day (morning and afternoon) of BC showed that BC decreases with height up to $600 m and then increases up to 900 m before becoming more or less constant with height. Potential temperature profile, derived from concurrent measurements of temperature, shows a stable layer at the same altitude where BC shows increased concentration. This vertical structure of boundary layer was further confirmed by separate temperature and relative humidity profiles obtained from balloonsondes during December. The increased BC at $900 m suggests the presence of enhanced BC layer, which will have significant implications to BC radiative forcing and modifying cloud properties.
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