In recent times, surface water resource in the Western Region of Ghana has been found to be inadequate in supply and polluted by various anthropogenic activities. As a result of these problems, the demand for groundwater by the human populations in the peri-urban communities for domestic, municipal and irrigation purposes has increased without prior knowledge of its water quality. Water samples were collected from 14 public hand-dug wells during the rainy season in 2013 and investigated for total coliforms, Escherichia coli, mercury (Hg), arsenic (As), cadmium (Cd) and physicochemical parameters. Multivariate statistical analysis of the dataset and a linear stoichiometric plot of major ions were applied to group the water samples and to identify the main factors and sources of contamination. Hierarchal cluster analysis revealed four clusters from the hydrochemical variables (R-mode) and three clusters in the case of water samples (Q-mode) after z score standardization. Principal component analysis after a varimax rotation of the dataset indicated that the four factors extracted explained 93.3 % of the total variance, which highlighted salinity, toxic elements and hardness pollution as the dominant factors affecting groundwater quality. Cation exchange, mineral dissolution and silicate weathering influenced groundwater quality. The ranking order of major ions was Na(+) > Ca(2+) > K(+) > Mg(2+) and Cl(-) > SO4 (2-) > HCO3 (-). Based on piper plot and the hydrogeology of the study area, sodium chloride (86 %), sodium hydrogen carbonate and sodium carbonate (14 %) water types were identified. Although E. coli were absent in the water samples, 36 % of the wells contained total coliforms (Enterobacter species) which exceeded the WHO guidelines limit of zero colony-forming unit (CFU)/100 mL of drinking water. With the exception of Hg, the concentration of As and Cd in 79 and 43 % of the water samples exceeded the WHO guideline limits of 10 and 3 μg/L for drinking water, respectively. Reported values in some areas in Nigeria, Malaysia and USA indicated that the maximum concentration of Cd was low and As was high in this study. Health risk assessment of Cd, As and Hg based on average daily dose, hazard quotient and cancer risk was determined. In conclusion, multiple natural processes and anthropogenic activities from non-point sources contributed significantly to groundwater salinization, hardness, toxic element and microbiological contamination of the study area. The outcome of this study can be used as a baseline data to prioritize areas for future sustainable development of public wells.

Abstract-The Lonar crater, India, is the only well-preserved simple crater on Earth in continental flood basalts; it is excavated in the Deccan trap basalts of Cretaceous-Tertiary age. A representative set of target basalts, including the basalt flows excavated by the crater, and a variety of impact breccias and impact glasses, were analyzed for their major and trace element compositions. Impact glasses and breccias were found inside and outside the crater rim in a variety of morphological forms and shapes. Comparable geochemical patterns of immobile elements (e.g., REEs) for glass, melt rock and basalt indicates minimal fractionation between the target rocks and the impactites. We found only little indication of post-impact hydrothermal alteration in terms of volatile trace element changes. No clear indication of an extraterrestrial component was found in any of our breccias and impact glasses, indicating either a low level of contamination, or a non-chondritic or otherwise iridium-poor impactor.

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Metagraywackes and metapelites from the Paleoproterozoic Birimian Supergroup in the Birim diamondiferous field, southern Ghana, were analyzed for their major and trace element contents. Compared to early Proterozoic crust, the metasedimentary rocks are enriched in ferromagnesian elements but depleted in rare earth elements (REE), high field strength elements (HFSE) (with exception of Zr), and Th. They show REE patterns similar to their Archean counterparts. The chemical data indicate that the sediments were derived from a local source of mixed felsic-mafic composition, with the latter dominating. The source rocks were the basaltic to dacitic volcanic rocks and granitoids within the Birimian greenstone belts. The chemical data further suggest their deposition in a tectonic setting comparable to modern island arcs, and that minimal old upper crust (i.e., pre-Birimian sources) was involved in their formation. The analyzed metasedimentary rocks have Eu-anomalies and Gd N /Yb N , Sm/Nd, Th/Sc, Cr/Sc and Cr/Th ratios that closely resemble those of their Archean counterparts, and therefore inconsistent with models suggesting abrupt compositional changes in upper crust at the Archean-Proterozoic boundary.