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The mononuclear title complex, [Mo(C9H9NO2)O2(H2O)], contains an Mo(VI) atom in a distorted octa­hedral coordination sphere defined by an Mo=O and an Mo—(OH2) bond to the axial ligands and two Mo—O bonds to phenolate and alcoholate O atoms, another Mo=O bond and one Mo—N bond to the imino N atom in the equatorial plane. The five-membered metalla-ring shows an envelope conformation. In the crystal, individual mol­ecules are connected into a layered arrangement parallel to (100) by means of O—H⋯O hydrogen bonds involving the water mol­ecule as a donor group and the O atoms of neighbouring complexes as acceptor atoms. These inter­actions lead to the formation of a three-dimensional network.

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