In stage I/II NK/T-cell lymphomas, when effective chemotherapeutic regimens were used, CCRT and sequential CT + RT gave similar outcome.
This letter is a report on hybrid double walled nanotubes (HDWNTs) of crystalline ferromagnetic nickel (Ni) nanotubes encapsulated conducting polypyrrole (PPy) nanotubes through a sequentially electrochemical synthetic method. Ferromagnetic Ni nanotubes were fabricated by an electrochemical deposition method outside the wall of the conducting PPy nanotubes. The formation and structure of HDWNTs of conducting PPy nanotubes and ferromagnetic Ni nanotubes were confirmed by transmission electron microscopy, high-resolution transmission electron microscopy, and elementary analysis. From the angular dependences of the magnetic hysteresis curves of the HDWNTs, the authors observed that the Ni nanotubes of the HDWNT systems had an anisotropic ferromagnetic nature with the maximum of coercivity and remanent-saturation magnetization when applying a magnetic field along the parallel direction of the tubes.
Amorphous vanadium oxide (V 2 O 5 ) is a very good candidate as material for cathode thin film since it has a relatively high capacity. In addition, the room temperature deposition process is valuable in V 2 O 5 thin film fabrication. Due to these advantages, much effort to grow amorphous V 2 O 5 thin film has been made. In this research, we successfully grew amorphous V 2 O 5 thin film using room temperature sputtering. Based on a Li/LiPON/V 2 O 5 full cell structure, charge-discharge performances were measured according to cycling number. Even though the full cell structure showed an average capacity of 15 μAh/cm 2 over more than 500 cycles, a capacity fade was shown after a few cycles. Many reports revealed that the phase change of V 2 O 5 from amorphous to crystalline made this kind of capacity fade. In order to investigate this phenomenon, high-resolution transmission electron microscopy (HRTEM) was employed. The as-deposited V 2 O 5 thin film consisted of a homogeneous amorphous without any grain-boundary and/or polycrystalline island. However, the microcrystalline V 2 O 5 phase was randomly distributed in the amorphous V 2 O 5 thin film matrix after 450 cycles by cross sectional TEM (XTEM). That is, some amorphous phase in the V 2 O 5 matrix changed to the crystalline phase. This crystalline phase strongly prevented the extraction of Li ions during the charge process, which induced the irreversible diffusion of Li ions from cathode to anode. From this result, a high efficiency thin film battery based on amorphous V 2 O 5 can be fabricated by preventing amorphous-crystal phase transformation during cycling.
To match the requirements for development of transformer cores with lower iron losses, many new materials are under development including amorphous materials, 6.5% Si–Fe sheets and thin gauged 3% Si–Fe sheets. Among these materials, the thin gauged 3% Si–Fe sheets are attracting attention due to their good magnetic properties and scientific interest. Arai et al. reported that the magnetic properties of the sheets were comparable to those of the amorphous materials and (110)[001] preferred orientation of the sheets are developed by tertiary recrystallization.1 The 100 μm thick 3% Si–Fe sheets were prepared via conventional metallurgical processes including melting and casting, hot rolling to 25 mmT at 1200 °C, first cold rolling to 0.5 mmT, intermediate annealing at 800 °C for 30 min, second cold rolling to 0.25 mmT, intermediate annealing at 800 °C for 30 min, final cold rolling to 100 μm and final annealing at 1200 °C for 1 h in a vacuum of 5×10−6 Torr. Among these processes, the cold rolling process is an important one because preferred orientation of the sheets was developed in the process. Nakano et al. reported that there was an optimum cold rolling ratio to get required magnetic properties of the sheets.2 Recently, we found that the reduction rate, i.e., number of passes, as well as reduction ratio affected the preferred orientation and magnetic properties of the sheets. The number of passes in the first cold rolling process was changed from 7 to 60 and B10 values of the final sheets were changed from 1.30 to 1.84 T according to the number of passes. From x-ray experiments, it was found that intensity of (110) peak in the cold rolled and annealed sheets strongly affected the magnetic properties of the final sheets. We will discuss the relationship between the reduction rate and preferred orientation, and magnetic properties of the thin gauged 3% Si–Fe sheets.
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