To mitigate the negative effects of pollution produced by the growing levels of pollutants in the environment, research and development of novel and more effective materials for the treatment of pollutants originating from a variety of industrial sources should be prioritized. In this research, a UV-irradiated nano-graphene oxide (UV/n-GO) was developed and studied for methylene blue (MB) adsorption. Furthermore, the batch adsorption studies were modelled using response surface modelling (RSM) and artificial neural networks (ANNs). Investigations employing FTIR, XRD, and SEM were carried out to characterize the adsorbent. The best MB removal of 95.81% was obtained at a pH of 6, a dose of 0.4 g/L, an MB concentration of 25 mg/L, and a period of 40 min. This was accomplished with a desirability score of 0.853. A three-layer backpropagation network with an ideal structure of 4-4-1 was used to create an ANN model. The R2 and MSE values determined by comparing the modelled data with the experimental data were 0.9572 and 0.00012, respectively. The % MB removal predicted by ANN was 94.76%. The kinetics of adsorption corresponded well with the pseudo-second-order model (R2 > 0.97). According to correlation coefficients, the order of adsorption isotherm models is Redlich–Peterson > Temkin > Langmuir > Freundlich. Thermodynamic investigations show that MB adsorption was both spontaneous and endothermic.
Plastics play a significant part in human life and the world we live in. The use of plastics results in detrimental effects on the natural world, which compels us to look for viable replacements. As a result of their enhanced capacity to biodegrade, bioplastics are becoming increasingly important materials. In recent years, there has been a rapid ascent in the utilization of biopolymers in various applications. The objective of this research is to investigate the impact that silica obtained from rice hull ash (RHA) and microcrystalline cellulose (MCC) obtained from groundnut husk have on the properties of bioplastic obtained from wheat gluten and fish scales. The usage of fish scales has been shown to have a positive effect on weight reduction and debasement rates. Microcrystalline cellulose (MCC) is utilized in a wide range of concentrations, and the influence of MCC on bioplastic is researched. The biodegradability tests of bioplastic revealed that the plastic lost 35% of its weight in just 14 days. The experiments that were done to evaluate the chemical stability and tensile strength of the bioplastic indicated that the MCC content has a significant effect in improving the characteristics of the material.
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