The absorption energies and the oscillator strengths of Z,-bands in the calcium doped crystals are theoretically investigated. The calculation is done by using both the polaron model of electron-excess centers and the valence-electron models of atom. The numerical rcsults are given for both the substitutional model and the Bushnell model. These results give an additional support to the general suggestion of Bushnell and lead to the conclusion that the Z,-band may be considered as the F-band perturbed by the complex consisting of a positive-ion vacancy and a divalent impurity.Die Absorptionsenergien nnd die Oszillatorst&rken der Z,-Banden in kalziumdotierten Kristallen werden theoretisch untersucht. Die Berechnungen werden mit dem Polaronenmodell der ElektroneniiberschuSzentren und dem Valenzelektronenmodell der Atome durchgefiihrt. Numerische Ergebnisse werden fur das Substitutionsmodell und das Bushnellsche Modell gegeben. Diese Ergebnisse liefern eine zusltxliche Stiitze fur die allgemeine Vorstcllung von Bushnell und fuhren zu dem SchluS, da13 die Z,-Bande als F-Bande angesehen werden kann, die durch die komplizierte Vcrbindung einer positiven Ionenleerstelle mit eincni zweiwertigen Fremdatom gestort ist.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.
customersupport@researchsolutions.com
10624 S. Eastern Ave., Ste. A-614
Henderson, NV 89052, USA
This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.
Copyright © 2024 scite LLC. All rights reserved.
Made with 💙 for researchers
Part of the Research Solutions Family.