Recent awareness of suspected adverse health effects from ambient particulate matter (PM) emission has prompted publication of new standards for fine PM with aerodynamic diameter less than 2.5 µm (PM 2.5 ). However, scientific data on fine PM emissions from various point sources and their characteristics are very limited. Source apportionment methods are applied to identify contributions of individual regional sources to tropospheric particulate concentrations. The existing industrial database developed using traditional source measurement techniques provides total emission rates only, with no details on chemical nature or size characteristics of particulates. This database is inadequate, in current form, to address source-receptor relationships.A source dilution system was developed for sampling and characterization of total PM, PM 2.5 , and PM 10 (i.e., PM with aerodynamic diameter less than 10 µm) from residual oil and coal combustion. This new system has automatic control capabilities for key parameters, such as relative humidity (RH), temperature, and sample dilution. During optimization of the prototype equipment, three North American coal blends were burned using a 0.7-megawatt thermal (MW t ) pulverized coal-fired, pilot-scale boiler. Characteristic emission profiles, including PM 2.5 and total PM soluble acids, and elemental and carbon concentrations for three coal blends are presented.Preliminary results indicate that volatile trace elements such as Pb, Zn, Ti, and Se are preferentially enriched in PM 2.5 . PM 2.5 is also more concentrated in soluble sulfates relative to total PM. Coal fly ash collected at the outlet of the electrostatic precipitator (ESP) contains about 85-90% PM 10 and 30-50% PM 2.5 . Particles contain the highest elemental concentrations of Si and Al while Ca, Fe, Na, Ba, and K also exist as major elements. Approximately 4-12% of the materials exists as soluble sulfates in fly ash generated by coal blends containing 0.2-0.8% sulfur by mass. Source profile data for an eastern U.S. coal show good agreement with those reported from a similar study done in the United States. Based on the inadequacies identified in the initial sampling equipment, a new, plume-simulating fine PM measurement system with modular components for field use is being developed for determining coal combustion PM source profiles from utility boiler stacks. INTRODUCTIONA considerable increase in scientific and regulatory discussions and research activities has been noted since new fine particulate standards were published in North America.

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