The current trend of industrial concrete leans more towards the use of self-compacting concrete. These must have fresh properties well defined as fluidity, filling ability and resistance to segregation. However, to ensure the rheological stability, use mineral fines is required. In this work, powder of calcined pyrophyllite (CP) was used as cement substitution at level of 10% and 20% by weight. The interest is focused on the role played by the calcined pyrophyllite to produce SCC with reduced impact environmental.. Calcination of pyrophyllite powder was carried out at 750 °C. Its effect on the workability and mechanical properties of self-compacting concrete is analyzed. The results show that the properties of workability of SCC containing 10% of calcined pyrophyllite tested at fresh state (Slump Flow, T50, passing ability and segregation resistance) are almost identical to those of the control SCC. Furthermore, the calcined pyrophyllite increases the compressive strength, tensile and flexural strength of SCC approaching without exceeding those of the control SCC. It seems that 10 % of calcined pyrophyllite is the optimum replacement rate which improves mechanical strength compared to 20%. Replacing cement with the calcined pyrophyllite aims to save cement and reduce the CO2 emissions released during the manufacture of cement.
In this work, an experimental investigation was carried out to evaluate the potential of an industrial pozzolan, the metakaolin, on the behavior of mortar. The aim is to use metakaolin as a 10% partial replacement of cement. Its effect on the physico-mechanical properties of the mortar has been analyzed. The results show that the incorporation of metakaolin decreases the density of the dried mortar and increases that of the wet mortar but these remain lower than those of the control mortar. Moreover, thermal analysis ATD / ATG shows that in the heat flow curve appears two endothermic peaks which correspond to the loss of mass of the cement pastes. Heat flux of these pastes increases when metakaolin is used into the cement. In addition, metakaolin increases the compressive and flexural strengths of wet and dry mortars by approaching without exceeding those of the control mortar. The use of metakaolin as a cement substitution has shown its potential to be a pozzolanic material that can offer economic, environmental and technical benefits.
In this paper, influence of heat treatment on evolution of mechanical strengths at early age, less than 24hours of self-compacting concretes containing limestone powder and silica fume as fine materials was investigated experimentally. Two compositions of self-compacting concrete have been studied; the first is elaborated with silica fume addition and the second with limestone powder, each mixture were prepared with a constant water/binder ratio of 0.39. Concrete samples were either cured in water at (23±1°C), or steam cured at 65°C maximum temperature over six hours (6h) curing period. Tests of mechanical strengths were performed on specimens cooled down slowly to room temperature after heating.The obtained results show that all self-compacting mixtures exhibited satisfying fresh properties and check EFNARC specifications of self-compacting concrete (slump flow diameter higher than 650mm, L-box ratio higher than 80% and sieve stability less than 17%).Mechanical strengths of concrete containing limestone addition are slightly lower than those of concrete based on silica fume at all ages. Moreover, heat treatment generates an improvement of compressive and flexural strength. Interesting compressive strengths are obtained. At 24 hours, after heat treatment, the strengths are already greater than 35 MPa. The values are 37 MPa and 40 MPa for self-compacting concrete containing limestone powder and silica fume respectively compared to 40 MPa and 46 MPa obtained at 7 days for the corresponding non-heat treated concretes. Compressive strength gain of SCCs mixtures with limestone powder and with silica fume, undergoing heat treatment at the age of 24hours is 85% and 75% respectively compared to SCCs mixtures cured in water.
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