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Purpose The purpose of this study is to evaluate and compare the mechanical performance of FFF parts when subjected to post processing thermal treatment. Therefore, a study of the annealing treatment influence on the mechanical properties was performed. For this, two different types of Nylon (PA12) were used, FX256 and CF15, being the second a short fibre reinforcement version of the first one. Design/methodology/approach In this study, tensile and flexural properties of specimens produced via FFF were determined after being annealed at temperatures of 135°C, 150°C or 165°C during 3, 6, 12 or 18 h and compared with the non-treated conditions. Differential scanning calorimetry (DSC) was performed to determine the degree of crystallinity. To evaluate the annealing parameters’ influence on the mechanical properties, a full factorial design of experiments was developed, followed by an analysis of variance, as well as post hoc comparisons, to determine the most significative intervening factors and their effect on the results. Findings The results indicate that CF15 increased its tensile modulus, strength, flexural modulus and flexural strength around 11%, while FX256 presented similar values for tensile properties, doubling for flexural results. Flexural strain presented an improvement, indicating an increased interlayer behaviour. Concerning to the DSC analysis, an increase in the degree of crystallinity for all the annealed parts. Originality/value Overall, the annealing treatment process cause a significant improvement in the mechanical performance of the material, with the exception of 165°C annealed specimens, in which a decrease of the mechanical properties was observed, resultant of material degradation.

Carbon nanoparticles tend to form agglomerates with considerable cohesive strength, depending on particle morphology and chemistry, thus presenting different dispersion challenges. The present work studies the dispersion of three types of graphite nanoplates (GnP) with different flake sizes and bulk densities in a polypropylene melt, using a prototype extensional mixer under comparable hydrodynamic stresses. The nanoparticles were also chemically functionalized by covalent bonding polymer molecules to their surface, and the dispersion of the functionalized GnP was studied. The effects of stress relaxation on dispersion were also analyzed. Samples were removed along the mixer length, and characterized by microscopy and dielectric spectroscopy. A lower dispersion rate was observed for GnP with larger surface area and higher bulk density. Significant re-agglomeration was observed for all materials when the deformation rate was reduced. The polypropylene-functionalized GnP, characterized by increased compatibility with the polymer matrix, showed similar dispersion effects, albeit presenting slightly higher dispersion levels. All the composites exhibit dielectric behavior, however, the alternate current (AC) conductivity is systematically higher for the composites with larger flake GnP.

Pristine and functionalized multiwalled carbon nanotubes (MWCNTs) with tailored interfaces were efficiently dispersed in an epoxy matrix using a three‐roll mill and further reinforced with carbon fibres. 1.3‐Dipolar cycloaddition of azomethine ylides was used for the chemical modification of MWCNTs by a solvent‐free approach. The influence of different loadings and types of MWCNTs on the final properties of the epoxy matrix was studied. Moreover, the most promising formulations were selected for manufacturing of prepreg sheets. The transversal tensile properties and the interlaminar fracture toughness under mode I loading (GIC) of multiscale carbon fibre–reinforced polymer (CFRP) composites were characterized. The results point out that it is not straightforward to transfer the remarkable intrinsic properties of MWCNTs to the composite level, although an overall positive trend was found. Double cantilever beam experiments showed that GIC of CFRP composites was improved 44% at ultralow content of functionalized MWCNTs (0.043 wt%).

Polymer nanocomposites are often prepared by melt compounding due to the suitability of the latter to industrial scale production. Even though monitoring the production process for quality control and/or optimization purposes is generally done off-line, the possibility of using on-line oscillatory rheometry has many inherent advantages. This work illustrates the use of a prototype rheometer to monitor the production of polymer nanocomposites by making measurements at specific locations along the extruder axis. The device is presented and its operation is explained. Examples of its use to characterize polypropylene and polyamide matrix nanocomposites with organoclays and carbon nanotubes are discussed, thus demonstrating the usefulness of the device.