Acrylonitrile butadiene styrene (ABS) is the most commonly used thermoplastic printing material for fused deposition modelling (FDM). FDM ABS can be used in a variety of complex working environments. Notably, the thermo-mechanical coupled loads under complex operating conditions may lead to cracking and ultimately catastrophic structural failure. Therefore, it is crucial to determine the crack depth and location before a structural fracture occurs. As these parameters affect the dynamic response of the structure, in this study, the fundamental frequency and displacement amplitude response of a cracked 3D-printed ABS cantilever beam in a thermal environment were analytically and experimentally investigated. The existing analytical model, specifically the torsional spring model used to calculate the fundamental frequency change to determine the crack depth and location was enhanced by the proposed Khan-He model. The analytical relationship between the displacement amplitude and crack was established in Khan-He model and validated for the first time for FDM ABS. The results show that a reduced crack depth and location farther from the fixed end correspond to a higher fundamental frequency and displacement amplitude. An elevated ambient temperature decreases the global elastic modulus of the cracked beam and results in a lower fundamental frequency. Moreover, a non-monotonic relationship exists between the displacement amplitude and ambient temperature. The displacement amplitude is more sensitive to the crack change than the fundamental frequency in the initial stages of crack growth.
The advantage of mesophase pitch-based carbon fibres is their high modulus, but pitch-based carbon fibres and precursors are very brittle. This paper reports the development of a unique manufacturing method using a blend of pitch and linear low-density polyethylene (LLDPE) from which it is possible to obtain precursors that are less brittle than neat pitch fibres. This study reports on the structure and properties of pitch and LLDPE blend precursors with LLDPE content ranging from 5 wt% to 20 wt%. Fibre microstructure was determined using scanning electron microscopy (SEM), which showed a two-phase region having distinct pitch fibre and LLDPE regions. Tensile testing of neat pitch fibres showed low strain to failure (brittle), but as the percentage of LLDPE was increased, the strain to failure and tensile strength both increased by a factor of more than 7. DSC characterisation of the melting/crystallization behaviour of LLDPE showed melting occurred around 120 °C to 124 °C, with crystallization between 99 °C and 103 °C. TGA measurements showed that for 5 wt%, 10 wt% LLDPE thermal stability was excellent to 800 °C. Blend pitch/LLDPE carbon fibres showed reduced brittleness combined with excellent thermal stability, and thus are a candidate as a potential precursor for pitch-based carbon fibre manufacturing.
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