Low voltage actuators based on poly(vinylidene fluoride) (PVDF) with 10, 25 and 40 % 1-hexyl-3-methylimidazolium chloride ([C6mim][Cl]) and 1-hexyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([C6mim][NTf2]) are prepared by solvent casting in order to evaluate the effect of anion size in the bending properties. Independently of the ionic liquid type and content, its presence leads to the crystallization of PVDF in the phase. The addition of ionic liquid into the polymer matrix decreases significantly its degree of crystallinity and the elastic modulus. It is also confirmed the good miscibility between PVDF and IL, determined by the interaction of the CF2 groups from the PVDF chains with the imidazolium ring in the ionic liquid (IL). The AC conductivity of the composites depends both on the amount of ionic liquid content and anion size. The bending movement of the IL/PVDF composites is correlated to their degree of crystallinity, mechanical properties and ionic conductivity value and the best value of bending response (0.53 %) being found for IL/PVDF composite with 40 wt% of [C6mim][Cl] at an applied voltage of 10 volts square signal.

Actuators based on polymer blends of poly(vinylidene fluoride) (PVDF) with 40 % of different ionic liquids (IL) are prepared by solvent casting. NTf2] were selected in order to evaluate the effect of anion and cation sizes in the bending properties. The microstructure, mechanical and electrical properties of the blend depend on the IL type, which in turn leads to a different bending response. In particular, the mechanical properties are independent on the IL type but the AC conductivity of the composites depend more on the anion type than on the size of the alkyl chain connected to the imidazolium based cation. Thus, the bending response of the IL/PVDF composites is correlated with the anion and cation sizes and a maximum bending response of 0.3 % is

In this contribution, a new concept of voltammetric catechol biosensor, based on the encapsulation of laccase (LAC) in a chitosan+lambda‐carrageenan (CHIT+CAR) polyelectrolyte complex (PEC) employing a simple coacervation process is presented. Chitosan (CHIT) was prepared from α‐chitin extracted from shrimp shells and lambda‐carrageenan (CAR) was extracted from red algae, both polysaccharides and PEC being characterized using FTIR spectrometry and electrochemistry. Cyclic voltammetry was utilized to determine the analytical features of the laccase (LAC) biosensor for catechol detection. The linear range was from 10−20 M to 10−14 M with a sensitivity of 1.55 mA/p[catechol] and a limit of detection of 3×10−21 M.The laccase biosensor exhibits good repeatability (RSD 2.38 %) and stability (four weeks). The developed biosensor was tested by applying it to the evaluation of the total polyphenolic content in natural oil samples.

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