1) constructed under the premises of the dual sitebond model have been used as probe substrates to study the effects of variable connectivity and pore-size correlation on the aspects of both hysteresis loops and primary sorption scanning curves. The shapes of the hysteresis loops obtained from sorption simulation in networks of diverse morphologies are compared and discussed. It is found that the precursor structural parameters of the Monte Carlo simulated networks together with the sorption algorithm used in this work, can lead to IUPAC types H1, H2 and H3-like hysteresis loops, depending on the values chosen for the pore-size distribution parameters and mean connectivity. Network morphology also influences greatly the mechanisms of sorption processes in poorly or highly size correlated porous substrates. Sorption results on these 3-D porous specimens help to visualize the extents of pore blocking (vapour percolation) and delayed adsorption (liquid percolation) phenomena and also to foresee the most appropriate methods to ascertain the structure of porous materials.

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Menisci interactions can strongly affect the development of adsorption processes in mesoporous materials. Phenomena such as delayed and advanced adsorption represent outright manifestations of these interactions then leading to deceptive determinations of the pore-size distribution. At present, a characterization study involving simulated porous networks with qualities similar to those owned by real materials and in which the above processes can occur is still lacking. A Monte Carlo procedure is used to evaluate the extent of delayed and advanced adsorption in porous structures of assorted morphologies. This treatment allows a clear detection of the types of mesoporous structures that can experience the incidence of delayed and advanced adsorption.