Samhita Bhaumik scite author profile

The synthesis and characterization of the first unique binuclear manganese(I) salicylate complex is described. The structure of the complex is unequivocally established with the help of an X-ray crystallographic study. The structure consists of two [MnO 6 ] units, containing octahedral Mn I ions, linked together by a bridging salicylato (Hsal ) ) ligand and each Mn I is chelated with a (H 2 sal) ligand. The complex possesses a metal oxidation state of +1 and is a rare example of a noncarbonyl or cyanide complex of a binuclear Mn I species. The effective magnetic moment per binuclear molecule ( l eff: ) at 27°C is 8.07 l B; that also describes the manganese (+1) oxidation state.

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Synthesis and Characterization of Manganese(iv) Complexes Derived From the Direct Reaction of Manganese(ii) Acetate Tetrahydrate With Oxaloyldihydrazide and 2-Hydroxy-1-Naphthaldehyde

Lal

Adhikari

Kumar

et al. 2002

Synthesis and Reactivity in Inorganic and Metal-Organic Chemist

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Synthesis, characterization and crystal structure of manganese (IV) complex derived from salicylic acid

Lal¹,

Bhaumik

Lemtur³

et al. 2006

Inorganica Chimica Acta

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Synthesis and characterization of tris[N-(2-oxo-1-naphthylidene)glycinato]manganese( III) and its reaction products with oxygen, nitrogen and/or sulphur donors

Singh¹,

Bhaumik²,

Lal³

2007

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Samhita Bhaumik

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Synthesis and Crystal Structure of [Mn2(H2sal)2(Hsal)2(H2O)4]. First Example of the Reductive Synthesis of a Binuclear Manganese(I) Salicylate Complex

Synthesis and Characterization of Manganese(iv) Complexes Derived From the Direct Reaction of Manganese(ii) Acetate Tetrahydrate With Oxaloyldihydrazide and 2-Hydroxy-1-Naphthaldehyde

Synthesis, characterization and crystal structure of manganese (IV) complex derived from salicylic acid

Synthesis and characterization of tris[N-(2-oxo-1-naphthylidene)glycinato]manganese( III) and its reaction products with oxygen, nitrogen and/or sulphur donors

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