The present study pertains to magnetoelectric coupling and energy storage analysis of (1 − x)BiFe0.95Mn0.05O3-xBaTiO3 (BFMO-BT) with x = 0.1, 0.2, 0.3 lead free solid solutions. BFMO-BT solid solutions possessed a cubic structure as confirmed from powder XRD and the Rietveld refinement. A maximum ferroelectric polarization of 0.82 μC/cm2 was observed in BFMO-0.3BT. BFMO-0.3BT exhibited a maximum energy storage density (WU) of 1.97 J/cm3 and an energy conversion efficiency of 81.7%. Enhanced bulk magnetization was associated with the lattice defects; however, it decreased with increased BT content. For BFMO-0.3BT, temperature dependent susceptibility, dielectric measurement, and differential scanning calorimetry measurement revealed the magnetic transition temperature to be 275 °C, 293 °C, and 223 °C, respectively. The linear magnetoelectric coupling coefficient was measured by quantifying change in maximum polarization with respect to the applied magnetic field and was found to be 28.55 mV cm−1 Oe for BFMO-0.3BT. Conductivity measurements of BFMO-0.3BT revealed a maximum value of activation energy, i.e., 0.21 eV at 1 kHz.

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