This literature review covers the solubility and processability of fluoropolymer polyvinylidine fluoride (PVDF). Fluoropolymers consist of a carbon backbone chain with multiple connected C–F bonds; they are typically nonreactive and nontoxic and have good thermal stability. Their processing, recycling and reuse are rapidly becoming more important to the circular economy as fluoropolymers find widespread application in diverse sectors including construction, automotive engineering and electronics. The partially fluorinated polymer PVDF is in strong demand in all of these areas; in addition to its desirable inertness, which is typical of most fluoropolymers, it also has a high dielectric constant and can be ferroelectric in some of its crystal phases. However, processing and reusing PVDF is a challenging task, and this is partly due to its limited solubility. This review begins with a discussion on the useful properties and applications of PVDF, followed by a discussion on the known solvents and diluents of PVDF and how it can be formed into membranes. Finally, we explore the limitations of PVDF’s chemical and thermal stability, with a discussion on conditions under which it can degrade. Our aim is to provide a condensed overview that will be of use to both chemists and engineers who need to work with PVDF.

With the re-emergence of sodium ion batteries (NIBs), we discuss the reasons for the recent interests in this technology and discuss the synergies between lithium ion battery (LIB) and NIB technologies and the potential for NIB as a “drop-in” technology for LIB manufacturing. The electrochemical testing of sodium materials in sodium metal anode arrangements is reviewed. The performance, stability, and polarization of the sodium in these test cells lead to alternative testing in three-electrode and alternative anode cell configurations. NIB manufacturability is also discussed, together with the impact that the material stability has upon the electrodes and coating. Finally, full-cell NIB technologies are reviewed, and literature proof-of-concept cells give an idea of some of the key differences in the testing protocols of these batteries. For more commercially relevant formats, safety, passive voltage control through cell balancing and cell formation aspects are discussed.

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A multi-functional structure saves mass from a spacecraft by incorporating other functional subsystems into the structure. By using the structural properties of a non-structural element, inert structure may be eliminated, and the requirement to allot internal volume to the subsystem in question is removed. The current paper describes a multi-functional structure based on the secondary power system. By using commercially available plastic lithium-ion cells to form the core of a sandwich panel, inert mass is eliminated from both the structure and from the battery enclosure. The feasibility of the proposed multi-functional structure is demonstrated though vibration testing on a single cell, and the successful manufacture of a test panel. The work goes on to quantify the potential mass savings that may be achieved by using a multi-functional structure of this type. By varying a set of spacecraft attributes, the study identifies that small spacecraft with high power requirements have the potential to gain the most benefit from using a multi-functional structure of this type. © IMechE 2008

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