Fourier transform (FT)-Raman and Fourier transform infrared (FT-IR) spectra of 3-{[(4-fluorophenyl)methylene]amino}-2-phenylquinazolin-4(3H)-one were recorded and analyzed. The vibrational wavenumbers of the title compound were computed using the B3LYP/6-31G * basis and compared with the experimental data. The prepared compound was identified by NMR and mass spectra. The simultaneous IR and Raman activation of the C=O stretching mode shows a charge transfer interaction through a π -conjugated path. The first hyperpolarizability and infrared intensities are reported. The assignments of the normal modes are done by potential energy distribution (PED) calculations.

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During acid fracturing of carbonate reservoirs, the acid dissolves the rock, creating wormholes which increase fluid loss. Excessive fluid loss lowers the net pressure in the fracture limiting fracture extension, and adversely affects the conductivity of the fracture. To overcome this problem, multiple stages of polymer pads are usually pumped in acid fracturing treatments to reduce leak-off. In addition, synthetic polymers are commonly added to the acid to produce gelled or in-situ gelled acids. The objective of adding these polymers is to reduce leak-off, by increasing the viscosity of the acid. This in turn reduces the rate of mass transfer of the acid to the rock surface. However, several studies have shown that these polymers can cause formation damage. Moreover, the crosslinker can precipitate in the formation causing further damage. Efficient mixing of synthetic polymers in the field is also a concern, especially when the polymers are present in a solid form.To overcome problems associated with polymeric fluids, polymer-free fluids were used for the first time to acid fracture several vertical wells in a deep gas reservoir in Saudi Arabia. The acid fracture treatments consisted of several stages including: viscous pads, emulsified acid, in-situ acid and an inhibited acid. A visco-elastic surfactant system replaced the polymers used in the pad and the leak-off control acid (28 wt% HCl). Calcium chloride produced from acid reactions with the carbonate rock viscosifies the acid in-situ, reducing leak-off volume. ResultsThe pressure response to acid f racture treatments clearly indicates that the surfactant-based system is very effective in controlling acid leak-off during the treatment in wells with a bottom hole temperature of nearly 260 o F. Good leak-off control did help in maintaining a constant pumping rate throughout the treatment. Significant increases in both gas production and flowing wellhead pressures were achieved utilizing this new system. In addition, pumping operations were simplified by continuous mixing of the fluids. The nondamaging nature of the system enhanced production rates above expectations.

FT-IR and FT-Raman spectra of 4-chloro-2-(4-bromophenylcarbamoyl)phenyl acetate were recorded and analyzed. The vibrational wavenumbers and corresponding vibrational assignments were examined theoretically using the Gaussian03 set of quantum chemistry codes. The red shift of the NH stretching wavenumber in the infrared (IR) spectrum from the computed wavenumber indicates the weakening of the NH bond resulting in proton transfer to the neighbouring oxygen atom. The simultaneous IR and Raman activations of the C O stretching mode give the charge transfer interaction through a π -conjugated path. Optimized geometrical parameters of the title compound are in agreement with similar reported structures. From the optimized structure, it is clear that the hydrogen bonding decreases the double bond character of C O bond and increases the double bond character of the C-N bonds. The first hyperpolarizability, predicted infrared intensities and Raman activities are reported. The calculated first hyperpolarizability is comparable with the reported values of similar derivativesand is an attractive object for future studies of non-linear optics. The assignments of the normal modes are done by potential energy distribution (PED) calculations.

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