Biodiesel is an alternative to mineral fuels, with advantages such as biodegradability. However, this makes biodiesel unstable to oxidation. In this way, the use of natural or synthetic antioxidants is necessary. Although many studies have paid attention to the effect of these antioxidants on oxidation stability, not much literature about their effect of them on other properties (before and during storage) was found. The aim of this research study was to characterize biodiesel from corn and sunflower by adding two antioxidants, butylated hydroxyanisole (BHA) and tertbutylhydroquinone (TBHQ), in order to improve its oxidation stability. Moreover, the effect of oxidation on the parameters of biodiesel was studied by using extreme oxidation conditions to accelerate the oxidation process. Both antioxidants improved the oxidation stability of biodiesel, whereas some parameters were altered (viscosity and acid number), which could make this biofuel, if high concentrations of antioxidants are used, unsuitable for commercialization according to standards.Keywords BHA Á TBHQ Á Oxidation stability Á Viscosity Á Thermal analysis Á Fatty acid methyl esters J Am Oil Chem Soc (2020) 97: 201-212.
Inulin is a prebiotic ingredient that is being increasingly used in food formulations as fat replacer. The present manuscript focuses on the formation of gels formed from inulin aqueous dispersions, observing the effect of inulin content, ranging from 25 to 50 wt%, and of the presence of calcium salts (chloride, lactate) at different concentrations up to 5 wt% Gels are observed to be stronger and formed in a shorter time as the polysaccharide content is higher. Both backscattering and rheological techniques can be used to follow the gelation, being able to detect a significant initial setting stage at 25 wt% inulin content. When calcium salts are added, weakening of gels takes place, resulting in lower values of the storage and loss moduli, G' and G'', respectively, as well as in a reduction of the linear viscoelastic range. Moreover, gelation seems to be retarded on a large scale of time due to the presence of salt. Prebiotic gels containing calcium are of special interest for the development of functional foods, always considering the effect they exert on the rheology when formulating these products.
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