No abstract

Hydrogels immobilizing nitrifying bacteria with different thicknesses of 0.55 and 1.13 cm (HG-0.55 and HG-1.13, respectively) were produced. It was recognized that the thickness of media is a crucial parameter that affects both the stability and efficiency of wastewater treatment. Batch mode experiments were conducted to quantify specific oxygen uptake rate (SOUR) values at various total ammonium nitrogen (TAN) concentrations and pH levels. In the batch test, HG-0.55 exhibited 2.4 times higher nitrifying activity than HG-1.13, with corresponding SOUR values of 0.00768 and 0.00317 mg-O2/L mL-PVA min, respectively. However, HG-0.55 was more susceptible to free ammonia (FA) toxicity than HG-1.13, resulting in a reduction of 80% and 50% in SOUR values for HG-0.55 and -1.13, respectively, upon increasing the FA concentration from 15.73 to 118.12 mg-FA/L. Continuous mode experiments were conducted to assess the partial nitritation (PN) efficiency in practical applications, where continuous wastewater inflow maintains low FA toxicity through high ammonia-oxidizing rates. With step-wise TAN concentration increases, HG-0.55 experienced a gentler increase in FA concentration compared to HG-1.13. At a nitrogen loading rate of 0.78–0.95 kg-N/m3 day, the FA increase rate for HG-0.55 was 0.0179 kg-FA/m3 day, while that of HG-1.13 was 0.0516 kg-FA/m3 day. In the batch mode, where wastewater is introduced all at once, the high accumulation of FA posed a disadvantage for the FA-susceptible HG-0.55, which made it unsuitable for application. However, in the continuous mode, the thinner HG-0.55, with its larger surface area and high ammonia oxidation activity, proved to be suitable and demonstrated its effectiveness. This study provides valuable insights and a framework for the utilization strategy of immobilized gels in addressing the toxic effects of FA in practical processes.

Hydrogels immobilizing nitrifying bacteria with different thicknesses of 0.55 and 1.13 cm (HG-0.55 and HG-1.13, respectively) were produced. It was recognized that the thickness of media is a crucial process parameter that affects both the stability and efficiency of wastewater treatment. Batch mode experiments were conducted to quantify specific oxygen uptake rate (SOUR) values at various total ammonium nitrogen (TAN) concentrations and pH levels. In the batch test, HG-0.55 exhibited 2.4 times higher nitrifying activity than HG-1.13, with corresponding SOUR values of 0.00768 and 0.00317 mg-O2/L·mL-PVA·min, respectively. However, HG-0.55 was more susceptible to free ammonia (FA) toxicity than HG-1.13, resulting in a reduction of 80% and 50% in SOUR values for HG-0.55 and − 1.13, respectively, upon increasing the FA concentration from 15.73 to 118.12 mg-FA/L. Continuous mode experiments were conducted to assess the partial nitritation (PN) strategy's efficiency in practical applications, where continuous wastewater inflow maintains low FA toxicity through high ammonia-oxidizing rates. With step-wise TAN concentration increases, HG-0.55 experienced a gentler increase in FA concentration compared to HG-1.13. At a nitrogen loading rate of 0.78–0.95 kg-N/m3·day, the FA increase rate for HG-0.55 was 0.0179 kg-FA/m3·day, while that of HG-1.13 was 0.0516 kg-FA/m3·day. Despite its sensitivity to FA toxicity, the thinner HG-0.55 can enhance PN performance owing to its higher ammonia-oxidizing activity. FA susceptibility depends on hydrogel thickness in batch and continuous modes, with continuous mode favoring thin gel with high ammonia-oxidizing activity due to the decrease in FA accumulation.

In this study, we optimized and explored the effect of the conditions for synthesizing Fe-loaded food waste biochar (Fe@FWB) for Cr(VI) removal using the response surface methodology (RSM) and artificial neural network (ANN). The pyrolysis time, temperature, and Fe concentration were selected as the independent variables, and the Cr(VI) adsorption capacity of Fe@FWB was maximized. RSM analysis showed that the p-values of pyrolysis temperature and Fe concentration were less than 0.05, indicating that those variables were statically significant, while pyrolysis time was less significant due to its high p-value (0.2830). However, the ANN model results showed that the effect of pyrolysis time was more significant on Cr(VI) adsorption capacity than Fe concentration. The optimal conditions, determined by the RSM analysis with a lower sum of squared error than ANN analysis, were used to synthesize the optimized Fe@FWB (Fe@FWB-OPT) for Cr(VI) removal. From the equilibrium model fitting, the Langmuir model showed a better fit than the Freundlich model, while the Redlich–Peterson isotherm model overlapped. The Cr(VI) sorption capacity of Fe@FWB-OPT calculated from the Langmuir model was 377.71 mg/g, high enough to be competitive to other adsorbents. The kinetic Cr(VI) adsorption was well described by the pseudo-second-order and Elovich models. The XPS results showed that Cr adsorbed on the surface of Fe-FWB-OPT was present not only as Cr(VI) but also as Cr(III) by the reduction of Cr(VI). The results of Cr(VI) adsorption by varying the pH indicate that electrostatic attraction is a key adsorption mechanism.