We investigate a configurationally locked polyene (CLP) crystal 2‐(3‐(4‐hydroxystyryl)‐5,5‐dimethylcyclohex‐2‐enylidene)malononitrile (OH1) containing a phenolic electron donor, which also acts as a hydrogen bond donor. The OH1 crystals with orthorhombic space group Pna21 (point group mm2) exhibit large second‐order nonlinear optical figures of merit, high thermal stability and very favorable crystal growth characteristics. Higher solubility in methanol and a larger temperature difference between the melting temperature and the decomposition temperature of OH1 compared to analogous CLP crystals, are of advantage for solution and melt crystal growth, respectively. Acentric bulk OH1 crystals of large sizes with side lengths of up to 1 cm with excellent optical quality have been successfully grown from methanol solution. The microscopic and macroscopic nonlinearities of the OH1 crystals are investigated theoretically and experimentally. The OH1 crystals exhibit a large macroscopic nonlinearity with four times larger powder second harmonic generation efficiency than that of analogous CLP crystals containing dimethylamino electron donor. A very high potential of OH1 crystals for broadband THz wave emitters in the full frequency range of 0.1–3 THz by optical rectification of 160 fs pulses has been demonstrated.

All subaerial lavas at Mauna Kea Volcano, Hawaii, belong to the postshield stage of volcano construction. This stage formed as the magma supply rate from the mantle decreased. It can be divided into two substages: basaltic (∼240–70 ka) and hawaiitic (∼66–4 ka). The basaltic substage (Hamakua Volcanics) contains a diverse array of lava types including picrites, ankaramites, alkalic and tholeiitic basalt, and high Fe‐Ti basalt. In contrast, the hawaiitic substage (Laupahoehoe Volcanics) contains only evolved alkalic lavas, hawaiite, and mugearite; basalts are absent. Sr and Nd isotopic ratios for lavas from the two substages are similar, but there is a distinct compositional gap between the substages. Lavas of the hawaiitic substage can not be related to the older basalts by shallow pressure fractionation, but they may be related to these basalts by fractionation at moderate pressures of a clinopyroxene‐dominated assemblage. We conclude that the petrogenetic processes forming the postshield lavas at Mauna Kea and other Hawaiian volcanoes reflect movement of the volcano away from the hotspot. Specifically, we postulate the following sequence of events for postshield volcanism at Mauna Kea: (1) As the magma supply rate from the mantle decreased, major changes in volcanic plumbing occurred. The shallow magma chamber present during shield construction cooled and crystallized, and the fractures enabling magma ascent to the magma chamber closed. (2) Therefore subsequent basaltic magma ascending from the mantle stagnated within the lower crust, or perhaps at the crust‐mantle boundary. Eruptions of basaltic magma ceased. (3) Continued volcanism was inhibited until basaltic magma in the lower crust cooled sufficiently to create relatively low‐density, residual hawaiitic melts. Minor assimilation of MORB‐related wall rocks, reflected by a trend toward lower 206Pb/204Pb in evolved postshield lavas, may have occurred at this time. A compositional gap developed because magma ascent was not possible until a low‐density hawaiitic melt could escape from a largely crystalline mush. Eruption of this melt created aphyric hawaiite and mugearite lavas which incorporated cumulate gabbro, wherlite, and dunite xenoliths during ascent.

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[1] NE trending granitoid batholiths in South Korea are part of the huge Phanerozoic granitoid belt in east Asia. The crystallization ages of granitoid plutons show three episodes of Mesozoic magmatism in South Korea: Triassic (248 -210 Ma), , and Late Cretaceous-early Tertiary (110-50 Ma), with a Late Jurassic -Early Cretaceous ($50 m.y.) hiatus. The granitoid ages and kinematic analyses of the Mesozoic structures in South Korea suggest that the Middle Jurassic (180-170 Ma) dextral strike-slip ductile shear zones formed by the northwest (orthogonal) subduction of the Izanagi plate, whereas the Cretaceous sinistral faults formed by the northward (oblique) subduction of the same plate, which generally agree with proposed reconstruction of plate motions, albeit uncertain, around east Asia. Among the models proposed to explain magmatic lull in a continental arc, shallow angle subduction associated with high convergence rate and subduction of oceanic plateaus might be the probable cause for the magmatic hiatus in South Korea and Japan. The huge width ($500 km) of the east Asian granitoid belt may be explained by oceanward retreat of subduction zone in the Cretaceous in association with change in the movement direction of the subducting plate.

Broadband THz pulses have been generated in 2-[3-(4- hydroxystyryl)-5,5-dimethylcyclohex-2-enylidene]malononitrile (OH1) by optical rectification of sub-picosecond laser pulses. We show that OH1 crystals allow velocity-matched generation and detection of THz frequencies in the whole range between 0.3 and 2.5 THz for a pump laser wavelength range from 1200 to 1460 nm. OH1 crystals show a higher figure of merit for THz generation and detection in the optimized range compared to the benchmark inorganic semiconductor crystals ZnTe and GaAs and the organic ionic salt crystal 4-N,N-dimethylamino-4'-N'-methyl stilbazolium tosylate (DAST). The material shows a low THz absorption coefficient alpha3 in the range between 0.3 and 2.5 THz, reaching values lower than 0.2mm(-1) between 0.7 and 1.0 THz. This is similar as in ZnTe and GaAs, but much lower than in DAST in the respective optimum frequency range. A peak THz electric field of 100 kV/cm and a photon conversion efficiency of 11 percent have been achieved at a pump pulse energy of 45 microJ.