Part III of the series on cooking systems presents a qualitative description of cooking methods such as open pan cooking, pressure cooking, steam cooking, solar energy-based cooking, microwave cooking, etc. A large number of chemical and physical changes occur during the process of cooking. These changes have been comprehensively covered in published literature including some textbooks. An attempt has been made to discuss a brief coherent description regarding the changes occurring in starches, proteins, fats, etc. The kinetics of the cooking reaction has also been investigated. This information can be advantageously employed for developing a protocol for an optimum temperature–time program. Because the cooking process is practically thermally neutral, a good scope is available for the optimization of energy supply. It was also thought desirable to understand the kinetics of degradation of proteins, vitamins, anti-nutrients, and flavors in different cooking practices, including microwave ovens and pressure cookers. The mechanism of cooking of rice and lentils has been described. The cooking process involves first the transfer of water from bulk to the particle surface, where the resistance for transfer is provided by a thin film in the vicinity of grain (rice and lentils) surfaces. Second, water has to transfer from the external surface to swollen cooked mass to uncooked core. Finally, on the surface of the uncooked core, the cooking reaction occurs. All published literature regarding this mechanism has been systematically analyzed, and the procedure has been given regarding the rate controlling step(s) and the estimation of the overall rate of cooking. For this purpose, the mathematical models have been given and methods have been described for the quantitative evaluation of the model parameters. A substantial amount of additional work is needed on the mechanism of cooking and suggestions have been made for future research.
Sections 2–6 of Part I were devoted to the analysis of heat transfer characteristics of cookers. In all the experiments, only water was employed as a working medium. Now, we extend such an analysis to the actual cooking process in order to arrive at an improved cooking device. The major strategies for the optimization of energy utilization is to design appropriate insulation that has been obtained by two cover vessels. In order to select an air gap, the flow and temperature patterns in the air gap have been extensively analyzed using computational fluid dynamics (CFD). The flow pattern and heat transfer in cooking pots have also been analyzed by CFD. This has enabled us to design suitable internals for minimizing the stratification of temperature. The understanding of fluid mechanics has also given basis for selection of heat flux, gap between burner tip and cooker bottom, and temperature of flue gases leaving the cooker. Chemical engineering principles have been used for modeling and optimization. Kinetics have been obtained in batch cookers. The knowledge of kinetics, thermal mixing, axial mixing, and optimum selection of insulation have been employed for the development of continuous cookers. The continuous mode of operation also helps in saving of energy. Systematic data have been collected for the design and scale up of continuous cookers.
In the conventional cooking practice, where a pot or a pan is directly placed on a flame, the thermal energy efficiency is in the range of 10–25%. It was thought desirable to increase this efficiency up to 60% or more. The cooking systems can be of various sizes. In the developing world (85% of the world’s population), open pan cooking is largely still practiced at the family level (4–10 people) or at the community level (50–2000 people or more). The latter requirement is encountered in schools, homes for senior citizens, jails, social and/or religious centers (temples, mosques, churches), social and/or educational functions (conferences, marriages, celebrations, etc.), remand homes, etc. For these different types of final application, in the present work, cooking systems have been developed. A systematic work has has been reported regarding the effect of several parameters on thermal efficiency. The parameters include the cooker size, number of pots, size and aspect ratio of the pots, heat flux, flame size, flux–time relationship, insulating alternatives, etc. Local and global optima of the parameters have been obtained, resulting in thermal efficiency of about 70%.
The textile and dye industries require an enormous amount of water for processing and produce a large volume of wastewater. Generated wastewater had potential hazards and a threat to the aquatic biota. The present work investigates the decolorization of brilliant green dye using a combination of two advanced oxidation techniques viz sonocatalysis and photocatalysis (immersed lamp) known as sonophotocatalysis (3 L capacity). The efficiency of decolorization is further improved in the presence of various additives viz. copper oxide, zinc oxide, and sodium chloride. The maximum decolorization of brilliant green (BG) (94.8% in 120 min) obtained in the presence of zinc oxide. The total organic carbon of the treated samples was measured to monitor complete mineralization of BG. The sonophotocatalytic process (in the presence of zinc oxide) shows maximum mineralization. Synergic combination of two oxidation processes increased the production of oxidizing radicals. Continuous cleaning of catalyst surface (due to sonolysis effect) improves the activity of the catalyst for photolysis operation. The present work is highly useful for the development of a sonophotocatalytic process.
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