Developing
low-weight,
frugal, and sustainable power sources for resource-limited settings
appears to be a challenging proposition for the advancement of next-generation
sensing devices and beyond. Here, we report the use of centimeter-sized
simple wet fabric pieces for electrical power generation by deploying
the interplay of a spontaneously induced ionic motion across fabric
nanopores due to capillary action and simultaneous water evaporation
by drawing thermal energy from the ambient. Unlike other reported
devices with similar functionalities, our arrangement does not necessitate
any input mechanical energy or complex topographical structures to
be embedded in the substrate. A single device is capable of generating
a sustainable open circuit potential up to ∼700 mV, which is
further scaled up to ∼12 V with small-scale multiplexing (i.e.,
deploying around 40 numbers of fabric channels simultaneously). The
device is able to charge a commercial supercapacitor of ∼0.1
F which can power a white light-emitting diode for more than 1 h.
This suffices in establishing an inherent capability of functionalizing
self-powered electronic devices and also to be potentially harnessed
for enhanced power generation with feasible up-scaling.
We exploit the combinatorial advantage of electrokinetics and tortuosity of a cellulose-based paper network on laboratory grade filter paper for the development of a simple, inexpensive, yet extremely robust (shows constant performance for 12 days) 'paper-and-pencil'-based device for energy harvesting applications. We successfully achieve harvesting of a maximum output power of ∼640 pW in a single channel, while the same is significantly improved (by ∼100 times) with the use of a multichannel microfluidic array (maximum of up to 20 channels). Furthermore, we also provide theoretical insights into the observed phenomenon and show that the experimentally predicted trends agree well with our theoretical calculations. Thus, we envisage that such ultra-low cost devices may turn out to be extremely useful in energizing analytical microdevices in resource limited settings, for instance, in extreme point of care diagnostic applications.
We investigate electroosmotic flow of two immiscible viscoelastic fluids in a parallel plate microchannel. Contrary to traditional analysis, the effect of the depletion layer is incorporated near the walls, thereby capturing the complex coupling between rheology and electrokinetics. Toward ensuring realistic prediction, we show the dependence of electroosmotic flow rate on the solution pH and polymer concentration of the complex fluid. In order to assess our theoretical predictions, we have further performed experiments on electroosmosis of an aqueous solution of polyacrylamide (PAAm). Our analysis reveals that neglecting the existence of a depletion layer would result in grossly incorrect predictions of the electroosmotic transport of such fluids. These findings are likely to be of importance in understanding electroosmotically driven transport of complex fluids, including biological fluids, in confined microfluidic environments.
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